自修复防腐涂层

李熙宇; 周梦萌; 王淳; 苏悦; 李明雪

doi:10.14028/j.cnki.1003-3726.2026.26.171

您当前的位置：

首页 >

文章列表页 >

自修复防腐涂层

综述 | 更新时间：2026-07-06

- 自修复防腐涂层
- Self-healing Anti-corrosion Coatings
- 高分子通报 2026年39卷第7期页码：1148-1176
- 作者机构：
  
  河南大学化学与分子科学学院河南省多金属氧酸盐化学重点实验室　开封 475004
- 作者简介：
  
  suyue@henu.edu.cn
  limingxue@henu.edu.cn
- 基金信息：
  
  河南省教育厅重大科技攻关项目(25A150019;24B150006);河南省科技攻关项目(242102230122);河南省自然科学基金(222300420413)
- DOI：10.14028/j.cnki.1003-3726.2026.26.171
  中图分类号：
- 收稿：2026-05-27，
  
  录用：2026-06-04，
  
  网络首发：2026-06-26，
  
  纸质出版：2026-07-20
- 稿件说明：
移动端阅览
李熙宇, 周梦萌, 王淳, 苏悦, 李明雪. 自修复防腐涂层. 高分子通报, 2026, 39(7), 1148–1176.

Li, X. Y.; Zhou, M. M.; Wang, C.; Su, Y.; Li, M. X. Self-healing anti-corrosion coatings. Polym. Bull. (in Chinese), 2026, 39(7), 1148–1176.
李熙宇, 周梦萌, 王淳, 苏悦, 李明雪. 自修复防腐涂层. 高分子通报, 2026, 39(7), 1148–1176. DOI： 10.14028/j.cnki.1003-3726.2026.26.171.

Li, X. Y.; Zhou, M. M.; Wang, C.; Su, Y.; Li, M. X. Self-healing anti-corrosion coatings. Polym. Bull. (in Chinese), 2026, 39(7), 1148–1176. DOI： 10.14028/j.cnki.1003-3726.2026.26.171.

摘要

金属腐蚀是工业领域面临的严峻问题，传统防腐涂层因易受环境侵蚀和机械应力产生裂纹，导致防护性能下降和修复困难。自修复防腐涂层因具备智能修复特性——无需频繁人工干预即可自主恢复防腐功能，现已成为防腐领域的研究热点之一。本文对自修复防腐涂层进行了系统性的综述，重点分析了外援型与本征型这2大体系的分类、修复机制、制备方法及性能特点。外援型涂层借助微胶囊或纳米容器负载修复剂或缓蚀剂，涂层损伤时释放修复剂填补裂纹或缓蚀剂与基体反应形成保护膜，提升防腐性能，实现自修复。本征型涂层无需外部添加，依赖涂层自身的动态化学键以及形状记忆效应，即可通过键的可逆重组来实现损伤修复。

Abstract

Metal corrosion is a serious problem in the industrial field

and traditional anti-corrosion coatings are prone to cracking during service owing to mechanical stress or environmental erosion

leading to a decline in protective performance and difficulties in repair. Self-healing anti-corrosion coatings have become a key research focus in the field of corrosion protection owing to their intelligent repair characteristics

which autonomously restore anti-corrosion functions without frequent manual intervention. This paper systematically reviews the research progress of self-healing anti-corrosion coatings

focusing on the analysis of the repair mechanism

preparation methods

and performance characteristics of the two major systems

namely

externally assisted and intrinsically assisted coatings. With the help of microcapsules or nanocontainers loaded with restorative agents or corrosion inhibitors

when the coating is damaged

the restorative agents are released to fill the cracks

or the corrosion inhibitors react with the substrate to form a protective film

which improves the anticorrosion performance and realizes self-healing. Intrinsic coatings rely on the dynamic chemical bonding and shape memory effect of the coating itself and can repair damage through the reversible reorganization of these chemical bonds or molecular chain movement without external additives.

关键词

Keywords

references

Xu, L. Y. ; Wang, X. Y. ; Badin, G. ; Azarmi, F. ; Huang, Y. ; Daiber, E. P. ; Wilson, R. Optimizing material selection for wire arc thermal spraying of Al and Zn alloy metallized polymeric coating systems: microstructural analysis and mechanical property evaluation . Mater. Chem. Phys. , 2025 , 333 , 130423 .

Wu, H. ; Wang, L. W. ; Wang, Y. X. ; Tian, H. Y. ; Xin, Y. L. ; Hou, J. ; Cui, Z. Y. Comparative study of the corrosion behavior of base metal and welded joint of Ti-6Al-3Nb-2Zr-1Mo alloy in the acidic chloride environment . Corros. Sci. , 2025 , 244 , 112649 .

Ma, X. Q. ; Gong, B. L. ; Wang, T. G. ; Hou, J. L. ; Ji, S. X. ; Xu, Q. J. ; Cao, H. J. Toward self-healing two dimensional MXene coatings for corrosion protection on metals: design strategies and mechanisms . Adv. Colloid Interface Sci. , 2025 , 335 , 103340 .

Fan, B. ; Yang, J. ; Cao, L. ; Wang, X. ; Li, J. ; Yang, Y. ; Wang, Q. ; Zhang, P. ; Vogel, F. ; Li, W. ; Lin, Z. Revealing the impact of micro-SiO 2 filer content on the anti-corrosion performance of water-borne epoxy resin . Polymers , 2023 , 15 ( 15 ), 3273 .

Sun, X. M. ; Wei, J. H. ; Cao, W. K. ; Li, W. H. Metal-organic frameworks-based smart anti-corrosion composite coatings: Recent advances, mechanisms, and future perspectives . Prog. Org. Coat. , 2026 , 213 , 109902 .

Motamedi, M. ; Ramezanzadeh, M. ; Ramezanzadeh, B. ; Mahdavian, M. One-pot synthesis and construction of a high performance metal-organic structured nano pigment based on nanoceria decorated cerium(Ⅲ)-imidazole network (NC/CIN) for effective epoxy composite coating anti-corrosion and thermo-mechanical properties improvement . Chem. Eng. J. , 2020 , 382 , 122820 .

Keramatinia, M. ; Majidi, R. ; Ramezanzadeh, B. La-MOF coordination polymer: an effective environmentally friendly pH-sensitive corrosion inhibitive-barrier nanofiller for the epoxy polyamide coating reinforcement . J. Environ. Chem. Eng. , 2022 , 10 ( 5 ), 108246 .

Li, K. ; Han, L. ; Wang, X. M. ; Gao, F. ; Zhang, J. Y. ; Cheng, J. MOF-derived CoNC@rGO/amine-rich@rGO/fluorinated-epoxy nanocomposites with EMI shielding, mechanical robustness, superamphiphobicity and long-term anticorrosion properties . Chem. Eng. J. , 2023 , 455 , 140542 .

Murtaza, H. ; Zhao, J. M. ; Tabish, M. ; Wang, J. B. ; Mubeen, M. ; Zhang, J. F. ; Zhang, S. ; Fan, B. M. Protective and flame-retardant bifunctional epoxy-based nanocomposite coating by intercomponent synergy between modified CaAl-LDH and rGO . ACS Appl. Mater. Interfaces , 2024 , 16 ( 10 ), 13114 – 13131 .

Chen, Z. H. ; Yang, W. Z. ; Chen, Y. ; Yin, X. S. ; Liu, Y. Smart coatings embedded with polydopamine-decorated layer-by-layer assembled SnO 2 nanocontainers for the corrosion protection of 304 stainless steels . J. Colloid Interface Sci. , 2020 , 579 , 741 – 753 .

Davarpanah, A. ; Bahlakeh, G. ; Ramezanzadeh, B. Engineering a novel smart nano-carrier based on NH 2 -MIL-125 metal-organic framework (Ti-MOF) decorated 2D GO nano-platform for reaching a self-healing coating . Appl. Mater. Today , 2023 , 32 , 101844 .

Gu, S. H. ; Shi, H. W. ; Li, J. Y. ; Xu, H. ; Udoh, I. I. ; Liu, F. C. ; Han, E. H. Self-diagnosing and active protective dual-functional water-borne polyurethane coating based on smart mesoporous containers . Prog. Org. Coat. , 2023 , 183 , 107789 .

Li, W. Y. ; Xie, C. ; Zhang, P. ; Zhang, Z. H. ; Xue, M. S. ; Yin, Z. Z. ; Luo, Y. D. ; Hong, Z. Constructing dual-ligand Ce-MOF on graphene oxide modified with polydopamine endowing polyurethane coating with long-term smart anti-corrosion and mechanical robustness . J. Colloid Interface Sci. , 2025 , 680 , 173 – 190 .

Li, J. ; Wang, L. Y. ; Bai, H. H. ; Chen, C. C. ; Liu, L. H. ; Guo, H. L. ; Lei, B. ; Meng, G. Z. ; Yang, Z. ; Feng, Z. Y. Development of an eco-friendly waterborne polyurethane/catecholamine/sol-gel composite coating for achieving long-lasting corrosion protection on Mg alloy AZ31 . Prog. Org. Coat. , 2023 , 183 , 107732 .

Khan, A. ; Hassanein, A. ; Habib, S. ; Nawaz, M. ; Shakoor, R. A. ; Kahraman, R. Hybrid halloysite nanotubes as smart carriers for corrosion protection . ACS Appl. Mater. Interfaces , 2020 , 12 ( 33 ), 37571 – 37584 .

Yin, Q. Q. ; Wang, C. J. ; Liu, Y. Z. ; Liu, S. Y. ; Wang, J. X. ; Fan, W. H. ; Wang, X. Q. ; Wang, H. Y. A novel organic-inorganic two-dimensional filler for composite coating with excellent mechanical and high-pressure CO 2 anti-corrosion performance . Compos. Sci. Technol. , 2024 , 252 , 110631 .

Zhou, L. B. ; Zhang, Q. ; Feng, X. M. ; Rui, Z. Y. ; Guo, W. J. ; Zhang, Y. F. ; Li, W. L. ; Li, Z. L. Chloride ion-responsive active protection epoxy composite coatings realized by 2-mercaptobenzimidazole and 2-mercaptobenzothiazole intercalated Mg-Al layered double hydroxides . Corros. Sci. , 2024 , 234 , 112144 .

Jiang, Y. X. ; Yin, S. F. ; Zhang, Y. L. ; Liu, P. ; Li, H. ; Wu, L. K. ; Cao, F. H. Phytic acid–loaded Ce-based metal-organic frameworks enabling synergistic interfacial regulation for active/passive corrosion protection . Colloids Surf. A Physicochem. Eng. Aspects , 2026 , 737 , 139873 .

Olivieri, F. ; Castaldo, R. ; Cocca, M. ; Gentile, G. ; Lavorgna, M. Mesoporous silica nanoparticles as carriers of active agents for smart anticorrosive organic coatings: a critical review . Nanoscale , 2021 , 13 ( 20 ), 9091 – 9111 .

Yimyai, T. ; Crespy, D. ; Rohwerder, M. Corrosion-responsive self-healing coatings . Adv. Mater. , 2023 , 35 ( 47 ), 2300101 .

Beach, M. ; Davey, T. ; Subramanian, P. ; Such, G. Self-healing organic coatings – fundamental chemistry to commercial application . Prog. Org. Coat. , 2023 , 183 , 107759 .

Ruda, A. ; Lumod, R. ; Lalem, A. ; Lagbang, M. ; Lubguban, A. ; Petalcorin, G. ; Paylaga, G. ; Sayson, N. L. ; Capangpangan, R. ; Dumancas, G. ; Alguno, A. A review on smart self-healing anti-corrosion coatings for sustainable infrastructure . Mater. Today Commun. , 2026 , 52 , 115218 .

Udoh, I. I. ; Shi, H. W. ; Daniel, E. F. ; Li, J. Y. ; Gu, S. H. ; Liu, F. C. ; Han, E. H. Active anticorrosion and self-healing coatings: a review with focus on multi-action smart coating strategies . J. Mater. Sci. Technol. , 2022 , 116 , 224 – 237 .

Panahi, P. ; Khorasani, S. N. ; Mensah, R. A. ; Das, O. ; Neisiany, R. E. A review of the characterization methods for self-healing assessment in polymeric coatings . Prog. Org. Coat. , 2024 , 186 , 108055 .

Zheng, Y. Z. ; Cosgrove, D. J. ; Ning, G. High-resolution field emission scanning electron microscopy (FESEM) imaging of cellulose microfibril organization in plant primary cell walls . Microanal , 2017 , 23 ( 5 ), 1048 – 1054 .

Ahangaran, F. ; Hayaty, M. ; Navarchian, A. H. ; Pei, Y. T. ; Picchioni, F. Development of self-healing epoxy composites via incorporation of microencapsulated epoxy and mercaptan in poly(methyl methacrylate) shell . Polym. Test. , 2019 , 73 , 395 – 403 .

Wang, J. ; Gao, C. Z. ; Fang, J. J. ; Fang, L. ; Lu, C. H. ; Xu, Z. Z. Waterborne polyurethane composite coatings as UV-light converter and directional infrared light barrier for light and heat management in greenhouse . Prog. Org. Coat. , 2023 , 183 , 107697 .

Yang, W. J. ; Tao, X. ; Zhao, T. T. ; Weng, L. X. ; Kang, E. T. ; Wang, L. H. Antifouling and antibacterial hydrogel coatings with self-healing properties based on a dynamic disulfide exchange reaction . Polym. Chem. , 2015 , 6 ( 39 ), 7027 – 7035 .

Wang, X. ; Liu, F. ; Zheng, X. W. ; Sun, J. Q. Water-enabled self-healing of polyelectrolyte multilayer coatings . Angew. Chem. Int. Ed. , 2011 , 50 ( 48 ), 11378 – 11381 .

Binder, W. H. Self-Healing Polymers: From Principles to Applications . Hoboken, NJ : John Wiley & Sons , 2013 .

Chen, Q. Q. ; Lu, X. P. ; Serdechnova, M. ; Wang, C. ; Lamaka, S. ; Blawert, C. ; Zheludkevich, M. L. ; Wang, F. H. Formation of self-healing PEO coatings on AM50 Mg by in-situ incorporation of zeolite micro-container . Corros. Sci. , 2022 , 209 , 110785 .

Serdechnova, M. ; Kallip, S. ; Ferreira, M. G. S. ; Zheludkevich, M. L. Active self-healing coating for galvanically coupled multi-material assemblies . Electrochem. Commun. , 2014 , 41 , 51 – 54 .

Lasia, A. Electrochemical impedance spectroscopy and its applications. In: Modern Aspects of Electrochemistry . Boston: Kluwer Academic Publishers , 2005 . 143 – 248 .

Guo, Y. G. ; Wang, J. ; Zhang, D. W. ; Qi, T. ; Li, G. L. pH-responsive self-healing anticorrosion coatings based on benzotriazole-containing zeolitic imidazole framework . Colloids Surf. A Physicochem. Eng. Aspects , 2019 , 561 , 1 – 8 .

Speight, J. G. Oil and Gas Corrosion Prevention: From Surface Facilities to Reffneries . Gulf Professional Publishing , 2014 .

Gonzalez-Garcia, Y. ; Garcia, S. J. ; Mol, J. M. C. Electrochemical techniques for the study of self healing coatings . Active Protective Coatings . Dordrecht : Springer Netherlands , 2016 . 203 – 240 .

Ataei, S. ; Khorasani, S. N. ; Torkaman, R. ; Neisiany, R. E. ; Koochaki, M. S. Self-healing performance of an epoxy coating containing microencapsulated alkyd resin based on coconut oil . Prog. Org. Coat. , 2018 , 120 , 160 – 166 .

Xue, Y. ; Li, C. M. ; Liu, J. ; Tan, J. J. ; Su, Z. Z. ; Yang, Y. M. ; Zhang, G. X. ; Zhang, Q. Y. Fabrication and characterization of hierarchical microcapsules with multi-storage cells for repeatable self-healing . Colloids Surf. A Physicochem. Eng. Aspects , 2020 , 603 , 125201 .

郭逍遥 , 汤汉良 , 马晓阳 , 陈之善 , 郭伟杰 , 赖浩城 . 一种基于硫醇–环氧树脂反应的自修复涂层的设计 . 上海涂料 , 2022 , 60 ( 5 ), 22 – 25 .

Liu, T. H. ; Zhao, Y. Z. ; Deng, Y. N. ; Ge, H. H. Preparation of fully epoxy resin microcapsules and their application in self-healing epoxy anti-corrosion coatings . Prog. Org. Coat. , 2024 , 188 , 108247 .

Alizadegan, F. ; Eivaz Mohammadloo, H. ; Mirabedini, S. M. ; Asemabadi, Z. ; Sardari, A. Preparation of self-healing water-based epoxy coatings containing microcapsules, treated CeO 2 particles and 8HQS corrosion inhibitor, and study of their anti-corrosion properties . Prog. Org. Coat. , 2024 , 195 , 108660 .

Xiang, G. F. ; Tu, J. ; Xu, H. ; Ji, J. ; Liang, L. ; Li, H. Z. ; Chen, H. R. ; Tian, J. Q. ; Guo, X. D. Preparation and self-healing application of isocyanate prepolymer microcapsules . Coatings , 2022 , 12 ( 2 ), 166 .

Li, J. Y. ; Shi, H. W. ; Liu, F. C. ; Han, E. H. Self-healing epoxy coating based on tung oil-containing microcapsules for corrosion protection . Prog. Org. Coat. , 2021 , 156 , 106236 .

Liu, Y. P. ; Zhan, Y. C. ; Tian, L. M. ; Zhao, J. ; Sun, J. Y. Study on the anticorrosion and antifouling performance of magnetically responsive self-healing polyurethane coatings . Prog. Org. Coat. , 2024 , 186 , 108047 .

Yeganeh, M. ; Omidi, M. ; Rabizadeh, T. Anti-corrosion behavior of epoxy composite coatings containing molybdate-loaded mesoporous silica . Prog. Org. Coat. , 2019 , 126 , 18 – 27 .

Guo, C. B. ; Lian, Y. B. ; Huang, C. ; Chen, Z. Y. Sustained-release system based on BTA@MOF-5 for self-healing coating application . Colloids Surf. A Physicochem. Eng. Aspects , 2022 , 654 , 130139 .

Li, Y. L. ; Zhan, Y. Q. ; Chen, Y. W. ; Zhang, H. Y. ; Lei, Y. J. ; Jia, H. S. ; Zhu, F. ; Yang, X. L. The healable and early warning waterborne epoxy coatings integrated with graphene oxide and HMTNs nanocontainer loaded with 8-hydroxyquinoline for the long-term corrosion protection of Q235 steel . Colloids Surf. A Physicochem. Eng. Aspects , 2024 , 703 , 135258 .

Bao, Y. ; Wei, Y. M. ; Fu, R. ZnPA@ZIF-8 nanoparticles: synthesis, sustained release properties and anticorrosion performance . Colloids Surf. A Physicochem. Eng. Aspects , 2022 , 651 , 129776 .

Chen, Y. X. ; Wang, Q. ; Hou, L. F. ; Huang, H. ; Gao, Z. Q. ; Wei, Y. H. Self-warning and self-repairing mechanisms in functional coatings: a review . Exploration , 2025 , 5 ( 4 ), e20240066 .

Lee Hia, I. ; Chan, E. S. ; Chai, S. P. ; Pasbakhsh, P. A novel repeated self-healing epoxy composite with alginate multicore microcapsules . J. Mater. Chem. A , 2018 , 6 ( 18 ), 8470 – 8478 .

Yang, H. I. ; Kim, D. M. ; Yu, H. C. ; Chung, C. M. Microcapsule-type organogel-based self-healing system having secondary damage preventing capability . ACS Appl. Mater. Interfaces , 2016 , 8 ( 17 ), 11070 – 11075 .

Zhang, F. ; Ju, P. F. ; Pan, M. Q. ; Zhang, D. W. ; Huang, Y. ; Li, G. L. ; Li, X. G. Self-healing mechanisms in smart protective coatings: a review . Corros. Sci. , 2018 , 144 , 74 – 88 .

Wang, W. ; Xu, L. K. ; Li, X. B. ; Lin, Z. F. ; Yang, Y. ; An, E. P. Self-healing mechanisms of water triggered smart coating in seawater . J. Mater. Chem. A , 2014 , 2 ( 6 ), 1914 – 1921 .

Chen, Z. H. ; Scharnagl, N. ; Zheludkevich, M. L. ; Ying, H. J. ; Yang, W. Z. Micro/nanocontainer-based intelligent coatings: Synthesis, performance and applications—a review . Chem. Eng. J. , 2023 , 451 , 138582 .

Huang, H. T. ; Guo, J. Y. ; Li, J. ; Li, L. ; Zhao, Z. L. Surface characterization of X80 Steel and Its Aspergillus terreus induced corrosion behavior in marine environment. Int. J. Electrochem. Sci. , 2022 , 17 ( 9 ), 220923 .

Shchukin, D. G. ; Zheludkevich, M. ; Yasakau, K. ; Lamaka, S. ; Ferreira, M. G. S. ; Möhwald, H. Layer-by-layer assembled nanocontainers for self-healing corrosion protection . Adv. Mater. , 2006 , 18 ( 13 ), 1672 – 1678 .

Haddadi, S. A. ; Ramazani S A, A. ; Mahdavian, M. ; Arjmand, M. Epoxy nanocomposite coatings with enhanced dual active/barrier behavior containing graphene-based carbon hollow spheres as corrosion inhibitor nanoreservoirs . Corros. Sci. , 2021 , 185 , 109428 .

Wang, Q. ; Wang, W. ; Ji, X. H. ; Hao, X. P. ; Ma, C. C. ; Hao, W. ; Li, X. ; Chen, S. G. Self-healing coatings containing core-shell nanofibers with pH-responsive performance . ACS Appl. Mater. Interfaces , 2021 , 13 ( 2 ), 3139 – 3152 .

Wang, T. ; Tan, L. H. ; Ding, C. D. ; Wang, M. D. ; Xu, J. H. ; Fu, J. J. Redox-triggered controlled release systems-based bi-layered nanocomposite coating with synergistic self-healing property . J. Mater. Chem. A , 2017 , 5 ( 4 ), 1756 – 1768 .

Vimalanandan, A. ; Lv, L. P. ; Tran, T. H. ; Landfester, K. ; Crespy, D. ; Rohwerder, M. Redox-responsive self-healing for corrosion protection . Adv. Mater. , 2013 , 25 ( 48 ), 6980 – 6984 .

Ma, L. W. ; Wang, J. K. ; Zhang, D. W. ; Huang, Y. ; Huang, L. Y. ; Wang, P. J. ; Qian, H. C. ; Li, X. G. ; Terryn, H. A. ; Mol, J. M. C. Dual-action self-healing protective coatings with photothermal responsive corrosion inhibitor nanocontainers . Chem. Eng. J. , 2021 , 404 , 127118 .

Skorb, E. V. ; Skirtach, A. G. ; Sviridov, D. V. ; Shchukin, D. G. ; Möhwald, H. Laser-controllable coatings for corrosion protection . ACS Nano , 2009 , 3 ( 7 ), 1753 – 1760 .

包颖 . 基于双马来酰亚胺树脂制备高耐热电子封装材料 . 江南大学硕士学位论文 , 2023 .

Fang, Y. L. ; Li, J. C. ; Du, X. S. ; Du, Z. L. ; Cheng, X. ; Wang, H. B. Thermal- and mechanical-responsive polyurethane elastomers with self-healing, mechanical-reinforced, and thermal-stable capabilities . Polymer , 2018 , 158 , 166 – 175 .

Oehlenschlaeger, K. K. ; Mueller, J. O. ; Brandt, J. ; Hilf, S. ; Lederer, A. ; Wilhelm, M. ; Graf, R. ; Coote, M. L. ; Schmidt, F. G. ; Barner-Kowollik, C. Adaptable hetero Diels-Alder networks for fast self-healing under mild conditions . Adv. Mater. , 2014 , 26 ( 21 ), 3561 – 3566 .

Postiglione, G. ; Turri, S. ; Levi, M. Effect of the plasticizer on the self-healing properties of a polymer coating based on the thermoreversible Diels–Alder reaction . Prog. Org. Coat. , 2015 , 78 , 526 – 531 .

Chuo, T. W. ; Liu, Y. L. Furan-functionalized aniline trimer based self-healing polymers exhibiting high efficiency of anticorrosion . Polymer , 2017 , 125 , 227 – 233 .

Liu, J. C. ; Zhou, Z. ; Su, X. Z. ; Cao, J. C. ; Chen, M. J. ; Liu, R. Stiff UV-Curable self-healing coating based on double reversible networks containing diels-alder cross-linking and hydrogen bonds . Prog. Org. Coat. , 2020 , 146 , 105699 .

Cao, Y. ; Wang, X. Y. ; Wu, J. H. ; Xu, Y. T. ; Gerard, J. F. ; Jiang, L. Y. ; Zeng, B. R. ; Dai, L. Z. A novel self-healing and removable hexagonal boron nitride/epoxy coating with excellent anti-corrosive property based on Diels-Alder reaction . Prog. Org. Coat. , 2022 , 173 , 107209 .

Abdolah Zadeh, M. ; van der Zwaag, S. ; Garcia, S. J. Adhesion and long-term barrier restoration of intrinsic self-healing hybrid sol-gel coatings . ACS Appl. Mater. Interfaces , 2016 , 8 ( 6 ), 4126 – 4136 .

Lai, Y. ; Kuang, X. ; Zhu, P. ; Huang, M. M. ; Dong, X. ; Wang, D. J. Colorless, transparent, robust, and fast scratc h-self-healing elastomers via a phase-locked dynamic bonds design . Adv. Mater. , 2018 , 30 ( 38 ), 1802556 .

Zhao, D. L. ; Liu, S. S. ; Wu, Y. F. ; Guan, T. ; Sun, N. ; Ren, B. Y. Self-healing UV light-curable resins containing disulfide group: synthesis and application in UV coatings . Prog. Org. Coat. , 2019 , 133 , 289 – 298 .

Wu, J. X. ; Liu, X. C. ; Chen, L. J. ; Du, J. H. ; Ji, L. ; Peng, Y. H. ; Liu, L. ; Xu, Z. Y. ; Lin, X. F. ; Lin, W. J. ; Sun, Y. J. ; Yi, G. B. Rapid self-healing and high-mechanical-strength epoxy resin coatings incorporating dynamic disulfide bonds . ACS Appl. Polym. Mater. , 2024 , 6 ( 8 ), 4778 – 4788 .

Liu, J. C. ; Cao, J. C. ; Zhou, Z. ; Liu, R. ; Yuan, Y. ; Liu, X. Y. Stiff self-healing coating based on UV-curable polyurethane with a “hard core, flexible arm” structure . ACS Omega , 2018 , 3 ( 9 ), 11128 – 11135 .

Liu, T. ; Zhao, H. C. ; Zhang, D. W. ; Lou, Y. T. ; Huang, L. Y. ; Ma, L. W. ; Hao, X. P. ; Dong, L. ; Rosei, F. ; Lau, W. M. Ultrafast and high-efficient self-healing epoxy coatings with active multiple hydrogen bonds for corrosion protection . Corros. Sci. , 2021 , 187 , 109485 .

He, S. S. ; Chen, J. N. ; Gao, Y. J. ; Wu, C. G. ; Chen, Z. Y. ; Cen, H. Y. Design of self-healing and anticorrosion epoxy coating with active multiple hydrogen bonds based on grafted polyetheramine . J. Mater. Res. Technol. , 2024 , 33 , 458 – 470 .

Tao, J. Q. ; Dong, L. ; Wu, Y. L. ; Liu, X. D. ; Xie, J. H. ; Wu, H. ; Ran, Q. P. Fabrication of room temperature self-healing, robust superhydrophobic coatings via spraying dual cross-linking supramolecular silicone polymer/SiO 2 composite . Compos. Part B Eng. , 2024 , 273 , 111245 .

Chen, Y. ; Li, W. ; Pu, R. ; Chen, F. B. ; Cheng, Y. J. ; Liu, Y. ; Luo, D. ; Nie, S. Y. ; Gao, X. L. ; Shen, L. ; Gao, F. One polymer-multiple functions: waterborne dual dynamic polyacrylate networks for self-healing and recyclable adhesives and coatings . Chem. Eng. J. , 2025 , 526 , 171257 .

Auepattana-Aumrung, K. ; Crespy, D. Self-healing and anticorrosion coatings based on responsive polymers with metal coordination bonds . Chem. Eng. J. , 2023 , 452 , 139055 .

Xia, N. N. ; Zhang, D. H. ; Wu, Q. ; Zhang, Z. P. ; Rong, M. Z. ; Zhang, M. Q. Self-passivation/self-delivery/self-healing anticorrosion polymer coating for marine applications . J. Colloid Interface Sci. , 2025 , 678 , 494 – 502 .

Chen, S. J. ; Ren, Z. H. ; Chen, M. ; Chen, H. ; Zhuo, H. T. ; Zhong, H. Q. Self-repairing elastomer based on imidazole π - π stacking interaction . Smart Mater. Struct. , 2023 , 32 ( 11 ), 115026 .

Wu, P. H. ; Xie, C. H. ; Li, Y. Q. ; Huang, C. J. ; Xie, H. B. ; You, Y. Fatigue-resistant, self-healable and thermally conductive polyurethane composites based on the intrinsic π - π stacking interactions between boron nitrides and hard segments . Mater. Today Commun. , 2025 , 45 , 112228 .

Chen, Y. H. ; Wu, L. ; Yao, W. H. ; Wu, J. H. ; Serdechnova, M. ; Blawert, C. ; Zheludkevich, M. L. ; Yuan, Y. ; Xie, Z. H. ; Pan, F. S. “Smart” micro/nano container-based self-healing coatings on magnesium alloys: a review . J. Magnes. Alloys , 2023 , 11 ( 7 ), 2230 – 2259 .

张冰红 . 自修复聚氨酯防腐涂层的制备与性能研究 . 西安工业大学硕士学位论文 , 2023 .

Sabet-Bokati, Z. ; Sabet-Bokati, K. ; Russell, Z. ; Morshed-Behbahani, K. ; Ouanani, S. Anticorrosion shape memory-assisted self-healing coatings: A review . Prog. Org. Coat. , 2024 , 188 , 108193 .

Behl, M. ; Lendlein, A. Shape-memory polymers . Mater. Today , 2007 , 10 ( 4 ), 20 – 28 .

González-García, Y. ; Mol, J. M. C. ; Muselle, T. ; De Graeve, I. ; Van Assche, G. ; Scheltjens, G. ; Van Mele, B. ; Terryn, H. A combined mechanical, microscopic and local electrochemical evaluation of self-healing properties of shape-memory polyurethane coatings . Electrochim. Acta , 2011 , 56 ( 26 ), 9619 – 9626 .

Rong, J. C. ; Zhong, J. ; Yan, W. L. ; Liu, M. C. ; Zhang, Y. L. ; Qiao, Y. L. ; Fu, C. Q. ; Gao, F. ; Shen, L. ; He, H. F. Study on waterborne self-healing polyurethane with dual dynamic units of quadruple hydrogen bonding and disulfide bonds . Polymer , 2021 , 221 , 123625 .

Luo, X. F. ; Mather, P. T. Shape memory assisted self-healing coating . ACS Macro Lett. , 2013 , 2 ( 2 ), 152 – 156 .

Kopeć, M. ; Szczepanowicz, K. ; Mordarski, G. ; Podgórna, K. ; Socha, R. P. ; Nowak, P. ; Warszyński, P. ; Hack, T. Self-healing epoxy coatings loaded with inhibitor-containing polyelectrolyte nanocapsules . Prog. Org. Coat. , 2015 , 84 , 97 – 106 .

Zheng, Z. ; Huang, X. ; Schenderlein, M. ; Moehwald, H. ; Xu, G. K. ; Shchukin, D. G. Bioinspired nanovalves with selective permeability and pH sensitivity . Nanoscale , 2015 , 7 ( 6 ), 2409 – 2416 .

Fan, W. J. ; Li, W. H. ; Zhang, Y. ; Wang, W. ; Zhang, X. Y. ; Song, L. Y. ; Liu, X. J. Cooperative self-healing performance of shape memory polyurethane and alodine-containing microcapsules . RSC Adv. , 2017 , 7 ( 74 ), 46778 – 46787 .

Iannuzzi, M. ; Kovac, J. ; Frankel, G. S. A study of the mechanisms of corrosion inhibition of AA2024-T3 by vanadates using the split cell technique . Electrochim. Acta , 2007 , 52 ( 12 ), 4032 – 4042 .

Cheng, L. ; Liu, C. B. ; Zhao, H. C. ; Wang, L. P. Photothermal-triggered shape memory coatings with active repairing and corrosion sensing properties . J. Mater. Chem. A , 2021 , 9 ( 39 ), 22509 – 22521 .

Cheng, L. ; Liu, C. B. ; Zhao, H. C. ; Wang, L. P. Hierarchically self-reporting and self-healing photothermal responsive coatings towards smart corrosion protection . Chem. Eng. J. , 2023 , 467 , 143463 .

Liu, C. B. ; Cheng, L. ; Qian, B. ; Cui, L. Y. ; Zeng, R. C. Corrosion self-warning and repair tracking of polymeric coatings based on stimulus responsive nanosensors . Nanoscale , 2022 , 14 ( 23 ), 8429 – 8440 .

Alagi, P. ; Ghorpade, R. ; Choi, Y. J. ; Patil, U. ; Kim, I. ; Baik, J. H. ; Hong, S. C. Carbon dioxide-based polyols as sustainable feedstock of thermoplastic polyurethane for corrosion-resistant metal coating . ACS Sustainable Chem. Eng. , 2017 , 5 ( 5 ), 3871 – 3881 .

Pathan, S. ; Ahmad, S. Synthesis, characterization and the effect of the s-triazine ring on physico-mechanical and electrochemical corrosion resistance performance of waterborne castor oil alkyd . J. Mater. Chem. A , 2013 , 1 ( 45 ), 14227 – 14238 .

Qian, H. C. ; Xu, D. K. ; Du, C. W. ; Zhang, D. W. ; Li, X. G. ; Huang, L. Y. ; Deng, L. P. ; Tu, Y. C. ; Mol, J. M. C. ; Terryn, H. A. Dual-action smart coatings with a self-healing superhydrophobic surface and anti-corrosion properties . J. Mater. Chem. A , 2017 , 5 ( 5 ), 2355 – 2364 .

Yang, Y. ; Urban, M. W. Self-healing polymeric materials . Chem. Soc. Rev. , 2013 , 42 ( 17 ), 7446 .

Zhao, X. ; Wei, J. F. ; Li, B. C. ; Li, S. B. ; Tian, N. ; Jing, L. Y. ; Zhang, J. P. A self-healing superamphiphobic coating for efficient corrosion protection of magnesium alloy . J. Colloid Interface Sci. , 2020 , 575 , 140 – 149 .

Liu, S. Q. ; Li, Z. X. ; Yu, Q. L. ; Qi, Y. M. ; Peng, Z. J. ; Liang, J. Dual self-healing composite coating on magnesium alloys for corrosion protection . Chem. Eng. J. , 2021 , 424 , 130551 .

Han, K. ; Liu, J. ; Hao, F. K. ; Wang, J. L. ; Yuan, J. F. ; Pan, Z. C. ; Pan, M. W. An adaptive waterborne fluorocarbon coatings with anti-flashing rust, antibiofouling, and self-repairing properties . Chem. Eng. J. , 2024 , 495 , 153644 .

Zhang, Y. Q. ; Zhao, Y. Z. ; Mu, X. L. ; He, W. P. ; Xiong, C. X. ; Wang, S. Robust self-healing polysulfide sealant via synergistic dynamic disulfide bonds and microencapsulated healing agents . Colloids Surf. A Physicochem. Eng. Aspects , 2025 , 726 , 138150 .

Lin, Z. H. ; Wang, X. ; Lu, W. ; Yang, F. ; Liu, Z. ; Zhou, K. Y. ; Li, B. Q. ; Huang, H. H. ; Zhang, C. C. ; Li, W. L. Dual-autonomous self-healing composite coating for steel with enhanced corrosion resistance: mechanism and performance evaluation . Prog. Org. Coat. , 2026 , 215 , 110119 .

Zhao, G. J. ; Zhang, Y. ; Chu, L. Y. ; Chen, K. ; Shen, L. M. ; Bao, N. Z. Benzotriazole-driven graphene oxide encapsulation technique for one-component microcapsule systems with ultrahigh performance . Ind. Eng. Chem. Res. , 2025 , 64 ( 1 ), 923 – 936 .

Cheng, L. ; Liu, C. B. ; Wu, H. ; Zhao, H. C. ; Wang, L. P. Interfacial assembled mesoporous polydopamine nanoparticles reduced graphene oxide for high performance of waterborne epoxy-based anticorrosive coatings . J. Colloid Interface Sci. , 2022 , 606 , 1572 – 1585 .

Zeng, C. ; Seino, H. ; Ren, J. ; Hatanaka, K. ; Yoshie, N. Bio-based furan polymers with self-healing ability . Macromolecules , 2013 , 46 ( 5 ), 1794 – 1802 .

Nardeli, J. V. ; Fugivara, C. S. ; Taryba, M. ; Montemor, M. F. ; Benedetti, A. V. Self-healing ability based on hydrogen bonds in organic coatings for corrosion protection of AA1200 . Corros. Sci. , 2020 , 177 , 108984 .

Lou, C. W. ; Wang, Y. ; Wang, Y. X. ; Zhang, X. F. ; Wang, Y. T. ; Wang, X. M. ; Ren, H. T. ; Li, T. T. ; Lin, J. H. ; Shiu, B. C. Ultrahigh tough, self-healing copolymer elastomer crosslinked by reversible imine system . Prog. Org. Coat. , 2023 , 185 , 107948 .

浏览量

149

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

红外自修复的基于动态亚胺键的苯胺低聚物修饰的聚二甲基硅氧烷摩擦纳米发电机

烯烃基自修复聚合物材料研究进展

可回收自修复聚氨酯的合成与性能调控

水凝胶在生物传感设备中的研究进展

守橡胶特色，筑学科高地——青岛科技大学高分子学科发展历程与建设现状