聚合物热电材料在自供能智能服饰中的研究进展

杨孟云; 金佳冰

doi:10.14028/j.cnki.1003-3726.2026.26.249

您当前的位置：

首页 >

文章列表页 >

聚合物热电材料在自供能智能服饰中的研究进展

综述 | 更新时间：2026-10-13

- 聚合物热电材料在自供能智能服饰中的研究进展
- Research Progress on Polymer Thermoelectric Materials in Self-powered Smart Clothing
- 高分子通报 2026年
- 作者机构：
  
  江西服装学院服装设计学院　南昌 330000
  江西服装学院南昌市轻工业产品人工智能制造重点实验室　南昌 330000
  江南大学纺织科学与工程学院　无锡 214000
- 作者简介：
  
  jiabing.jin@outlook.com
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2026.26.249
  中图分类号：
- 收稿：2026-05-15，
  
  录用：2026-06-21，
- 稿件说明：
移动端阅览
杨孟云, 金佳冰. 聚合物热电材料在自供能智能服饰中的研究进展. 高分子通报, doi: 10.14028/j.cnki.1003-3726.2026.26.249

Yang, M. Y.; Jin, J. B. Research progress on polymer thermoelectric materials in self-powered smart clothing. Polym. Bull. (in Chinese), doi: 10.14028/j.cnki.1003-3726.2026.26.249
杨孟云, 金佳冰. 聚合物热电材料在自供能智能服饰中的研究进展. 高分子通报, doi: 10.14028/j.cnki.1003-3726.2026.26.249 DOI：

Yang, M. Y.; Jin, J. B. Research progress on polymer thermoelectric materials in self-powered smart clothing. Polym. Bull. (in Chinese), doi: 10.14028/j.cnki.1003-3726.2026.26.249 DOI：

摘要

自供能智能服饰需要兼顾柔性穿戴、持续供能、信号感知、水洗耐久和皮肤安全。聚合物热电材料可利用人体与环境之间的低品位温差产生电能或自供能传感信号，具有低热导率、柔韧性好、可溶液加工和易于织物集成等优势。本文围绕聚合物热电材料在自供能智能服饰中的应用，综述了p型聚(3

4-乙烯二氧噻吩):聚苯乙烯磺酸盐(PEDOT:PSS)、聚合物/碳基复合体系、n型聚合物、聚合物多重异质结、印刷成型、热电纤维和三维织物热流管理等研究进展。重点分析了多胺去掺杂、界面能量过滤、n型聚苯并二呋喃二酮(PBFDO)缺陷抑制、界面热散射和纳米黏结剂印刷等关键机制。进一步结合低温差输出、响应时间、识别精度、机械循环、水洗耐久、汗液稳定性和生物相容性等指标，指出聚合物热电服饰评价可由功率因子(PF)或无量纲热电优值(ZT)等单一材料指标转向“材料参数–器件输出–穿戴可靠性”的综合评价体系。未来研究需加强热–电输运解耦、n型聚合物稳定化、三维热流管理和标准化可靠性测试，以推动聚合物热电材料在自供能智能服饰中的实际应用。

Abstract

Self-powered smart clothing requires conformable wearability

continuous energy harvesting

signal sensing

wash durability

and skin-contact safety. Polymer thermoelectric materials can convert the low-grade temperature difference between the human body and the environment into electrical energy or self-powered sensing signals. Their low thermal conductivity

mechanical flexibility

solution processability

and textile compatibility render them promising candidates for garment-integrated energy harvesters and passive sensors. This review summarizes recent progress in p-type poly(3

4-ethylenedioxythiophene): poly(styrene sulfonate) (PEDOT:PSS) systems

polymer/carbon composites

n-type polymers

polymeric multi-heterojunctions

printed thermoelectrics

thermoelectric fibers

and three-dimensional textile-based heat-flow management

with an emphasis on key mechanisms

including polyamine-induced dedoping

interfacial energy filtering

defect suppression in n-type poly(benzodifurandione) (PBFDO) polymers

interfacial thermal scattering

and nanobinder-assisted printing. By comparing the low-temperature-gradient output

response time

recognition accuracy

mechanical cycling

wash durability

sweat stability

and biocompatibility

this review emphasizes that polymer thermoelectric smart clothing should be evaluated using an integrated “material parameter–device output–wearable reliability” framework rather than by power factor (PF) dimensionless thermoelectric figure of merit (ZT) alone. Future studies should focus on thermal-electrical transport decoupling

n-type polymer stability

three-dimensional heat-flow management

and standardized reliability testing to promote practical applications in self-powered smart clothing systems.

关键词

Keywords

references

Yang, Y. ; Li, H. ; Xu, Z. ; Luo, S. Y. ; Chen, L. D . Wearable self-powered devices based on polymer thermoelectric materials . Moore More , 2025 , 2 ( 1 ), 4 .

He, X. Y. ; Shi, X. L. ; Wu, X. Y. ; Li, C. Z. ; Liu, W. D. ; Zhang, H. H. ; Yu, X. L. ; Wang, L. M. ; Qin, X. H. ; Chen, Z. G . Three-dimensional flexible thermoelectric fabrics for smart wearables . Nat . Commun . , 2025 , 16 , 2523 .

王子洵 , 魏传辉 , 吕天梅 , 王佩红 , 董凯 . 自供电可穿戴智能纺织品研究进展 . 纺织工程学报 , 2023 , 1 ( 6 ), 35 – 53 .

王思远 , 王军 . 柔性电子材料在可穿戴设备中的研究进展 . 纺织导报 , 2024, ( 3 ), 51 – 55 .

郑园园 , 韩雪 , 景媛媛 , 陈馨逸 , 张坤 . 纺织结构热电器件的设计制备及应用 . 纺织高校基础科学学报 , 2022 , 35 ( 1 ), 34 – 47 .

Suarez, F. ; Nozariasbmarz, A. ; Vashaee, D. ; Öztürk, M. C . Designing thermoelectric generators for self-powered wearable electronics . Energy Environ . Sci . , 2016 , 9 ( 6 ), 2099 – 2113 .

Chen, X. Y. ; Yang, X. N. ; Han, X. ; Ruan, Z. P. ; Xu, J. C. ; Huang, F. L. ; Zhang, K . Advanced thermoelectric textiles for power generation: principles, design, and manufacturing . Glob . Chall . , 2024 , 8 ( 2 ), 2300023 .

许子傲 , 吴雅梦 , 郭浩 , 俞建勇 , 丁彬 , 李召岭 . 纤维基摩擦纳米发电机的构建及其在可穿戴技术领域的研究进展 . 纺织工程学报 , 2023 , 12 ( 6 ), 71 – 85 .

Russ, B. ; Glaudell, A. ; Urban, J. J. ; Chabinyc, M. L. ; Segalman, R. A . Organic thermoelectric materials for energy harvesting and temperature control . Nat . Rev . Mater . , 2016 , 1 , 16050 .

Chen, W. Y. ; Shi, X. L. ; Li, M. ; Liu, T. ; Mao, Y. Q. ; Liu, Q. Y. ; Dargusch, M. ; Zou, J. ; Lu, G. Q. M. ; Chen, Z. G . Nanobinders advance screen-printed flexible thermoelectrics . Science , 2024 , 386 ( 6727 ), 1265 – 1271 .

郭凯 , 骆军 , 赵景泰 . 热电材料的基本原理、关键问题及研究进展 . 自然杂志 , 2015 , 37 ( 3 ), 175 – 187 .

黄轩 , 刘卓鑫 , 刘福生 , 陈光明 . 聚(3,4-乙烯二氧噻吩): 聚苯乙烯磺酸盐热电性能的提升策略研究进展 . 高分子学报 , 2021 , 52 ( 4 ), 339 – 349 .

Wang, D. Y. ; Ding, J. M. ; Ma, Y. Q. ; Xu, C. L. ; Li, Z. Y. ; Zhang, X. ; Zhao, Y. ; Zhao, Y. ; Di, Y. Q. ; Liu, L. Y. ; Dai, X. J. ; Zou, Y. ; Kim, B. ; Zhang, F. J. ; Liu, Z. T. ; McCulloch, I. ; Lee, M. ; Chang, C. ; Yang, X. ; Wang, D. ; Zhang, D. Q. ; Zhao, L. D. ; Di, C. A. ; Zhu, D. B . Multi-heterojunctioned plastics with high thermoelectric figure of merit . Nature , 2024 , 632 ( 8025 ), 528 – 535 .

钱伯章 . 我国科学家研制出高性能塑料基热电材料 . 合成材料老化与应用 , 2024 , 53 ( 5 ), 87 .

Luan, Y. D. ; Liao, J. Q. ; Cui, W. ; Wang, X. Y. ; Dai, T. Y. ; Wang, S. J. ; Liu, X. Y. ; Chen, S. ; Hou, B. M. ; Ye, F. ; Zhang, R. M. ; Ye, F. ; Zhang, R. ; Ding, R. ; Li, J. ; Guo, Z. H . Elemental sulfur mediated one-pot synthesis of poly(benzodifurandione) (PBFDO) with high conductivity for organic electronics . ChemRxiv , 2026 , DOI: 10.26434/chemrxiv.15000671/v2 https://doi.org/10.26434/chemrxiv.15000671/v2 .

Hwang, J. ; Zhao, Q. Y. ; Ahmed, M. ; Yakisan, A. C. ; Espenship, M. F. ; Laskin, J. ; Savoie, B. M. ; Mei, J. G . Reductive doping inhibits the formation of isomerization-derived structural defects in N-doped poly(benzodifurandione) (n-PBDF) . Angew . Chem . Int . Ed . , 2024 , 63 ( 18 ), e202401465 .

Floris, P. S. ; Zozoulenko, I. ; Rurali, R . Doping efficiency of poly(benzodifurandione) from first principles . J. Phys. Chem. C , 2025 , 129 ( 9 ), 4354 – 4357 .

Yemata, T. A. ; Kyaw, A. K. K. ; Zheng, Y. ; Xu, J. W. ; Chin, W. S. ; Zhu, Q. ; Hayashi, Y . Interface engineering in polymer thermoelectric composites: harnessing energy-filtering effects to overcome the seebeck-conductivity trade-off . J. Mater. Chem. A , 2025 , 13 ( 42 ), 35976 – 35998 .

Wang, Y. ; Zhang, Q. C. ; Zhang, Z. D . Dual-mode textile sensor based on PEDOT:PSS/SWCNTs composites for pressure-temperature detection . Micromachines , 2025 , 16 ( 1 ), 92 .

Ji, J. ; Luo, H. Y. ; Su, J. T. ; Wang, S. H. ; Chen, X. D. ; Song, J. Z . Multisensory electronic skin with decoupled pressure-temperature-sensing capabilities for similar object recognition . Proc . Natl . Acad . Sci . U . S . A . , 2025 , 122 ( 41 ), e2519693122 .

朱诗倩 , 谈伊妮 , 刘晓刚 . 柔性复合导电纤维在智能纺织品中的研究进展 . 现代纺织技术 , 2022 , 30 ( 4 ), 1 – 11 .

Bubnova, O. ; Khan, Z. U. ; Malti, A. ; Braun, S. ; Fahlman, M. ; Berggren, M. ; Crispin, X . Optimization of the thermoelectric figure of merit in the conducting polymer poly(3,4-ethylenedioxythiophene) . Nat . Mater . , 2011 , 10 ( 6 ), 429 – 433 .

Ryan, J. D. ; Mengistie, D. A. ; Gabrielsson, R. ; Lund, A. ; Müller, C . Machine-Washable PEDOT:PSS dyed silk yarns for electronic textiles . ACS Appl. Mater. Interfaces , 2017 , 9 ( 10 ), 9045 – 9050 .

Tseghai, G. B. ; Mengistie, D. A. ; Malengier, B. ; Fante, K. A. ; van Langenhove, L . PEDOT: PSS-based conductive textiles and their applications . Sensors , 2020 , 20 ( 7 ), 1881 .

Adamu, M. ; Nadeem, M. ; Hasnain, M. ; Ullah, A. ; Afzal, T. ; Fan, N. ; Bao, Y. R. ; Jiao, F . Enhanced thermoelectric performance of PEDOT: PSS/SWCNT/PDDA three-component composite films . RSC Adv . , 2025 , 15 ( 58 ), 50142 – 50150 .

Uchida, K. ; Shinozaki, Y. ; Nakayama, H. ; Ochiai, S. ; Nakazawa, Y. ; Takashiri, M . SWCNT/PEDOT: PSS/SA composite yarns with high mechanical strength and flexibility via wet spinning for thermoelectric applications . Sensors , 2025 , 25 ( 19 ), 6202 .

Liu, S. Q. ; Zhang, M. X. ; Kong, J. H. ; Li, H. ; He, C. B . Flexible, durable, green thermoelectric composite fabrics for textile-based wearable energy harvesting and self-powered sensing . Compos . Sci . Technol . , 2023 , 243 , 110245 .

Gao, X. Z. ; Gao, F. L. ; Liu, J. ; Li, Y. J. ; Wan, P. B. ; Yu, Z. Z. ; Li, X. F . Self-powered resilient porous sensors with thermoelectric poly(3,4-ethylenedioxythiophene): poly-(styrenesulfonate) and carbon nanotubes for sensitive temperature and pressure dual-mode sensing . ACS Appl. Mater. Interfaces , 2022 , 14 ( 38 ), 43783 – 43791 .

Li, M. F. ; Chen, J. X. ; Zhong, W. B. ; Luo, M. Y. ; Wang, W. ; Qing, X. ; Lu, Y. ; Liu, Q. Z. ; Liu, K. ; Wang, Y. D. ; Wang, D . Large-area, wearable, self-powered pressure-temperature sensor based on 3D thermoelectric spacer fabric . ACS Sens . , 2020 , 5 ( 8 ), 2545 – 2554 .

马珮珮 , 李龙 , 吴磊 . 导电纱线的制备及其在智能可穿戴装置中的应用研究进展 . 材料工程 , 2021 , 49 ( 10 ), 31 – 42 .

Darabi, S. ; Yang, C. Y. ; Li, Z. R. ; Huang, J. D. ; Hummel, M. ; Sixta, H. ; Fabiano, S. ; Müller, C . Polymer-based n-type yarn for organic thermoelectric textiles . Adv . Electron . Mater . , 2023 , 9 ( 4 ), 2201235 .

Sarabia-Riquelme, R. ; Noble, L. E. ; Alarcon Espejo, P. ; Ke, Z. F. ; Graham, K. R. ; Mei, J. G. ; Paterson, A. F. ; Weisenberger, M. C . Highly conductive n-type polymer fibers from the wet-spinning of n-doped PBDF and their application in thermoelectric textiles . Adv . Funct . Mater . , 2024 , 34 ( 9 ), 2311379 .

孙敏 , 路旭 , 袁刚 , 曹津维 , 卢荣泰 , 唐国武 , 陈东丹 , 钱奇 . 微纳热电纤维的研究进展 . 激光与光电子学进展 , 2023 , 60 ( 13 ), 1316012 .

Kim, Y. ; Lund, A. ; Noh, H. ; Hofmann, A. I. ; Craighero, M. ; Darabi, S. ; Zokaei, S. ; Park, J. I. ; Yoon, M. H. ; Müller, C . Robust PEDOT: PSS wet-spun fibers for thermoelectric textiles . Macromol . Mater . Eng . , 2020 , 305 ( 3 ), 1900749 .

Deng, Y. Y. ; Shi, X. L. ; Wu, T. ; Yue, Y. C. ; Liu, W. D. ; Li, M. ; Yue, F. ; Huang, P. ; Liu, Q. F. ; Chen, Z. G . Optimization of wet-spun PEDOT: PSS fibers for thermoelectric applications through innovative triple post-treatments . Adv . Fiber Mater . , 2024 , 6 ( 5 ), 1616 – 1628 .

Ding, T. P. ; Chan, K. H. ; Zhou, Y. ; Wang, X. Q. ; Cheng, Y. ; Li, T. T. ; Ho, G. W . Scalable thermoelectric fibers for multifunctional textile-electronics . Nat . Commun . , 2020 , 11 , 6006 .

He, X. Y. ; Gu, J. T. ; Hao, Y. N. ; Zheng, M. R. ; Wang, L. M. ; Yu, J. Y. ; Qin, X. H . Continuous manufacture of stretchable and integratable thermoelectric nanofiber yarn for human body energy harvesting and self-powered motion detection . Chem . Eng . J . , 2022 , 450 , 137937 .

Jing, Y. Y. ; Luo, J. ; Han, X. ; Yang, J. W. ; Liu, Q. L. ; Zheng, Y. Y. ; Chen, X. Y. ; Huang, F. L. ; Chen, J. W. ; Zhuang, Q. L. ; Shen, Y. N. ; Chen, H. S. ; Zhao, H. Z. ; Snyder, G. J. ; Li, G. D. ; Zhang, T. ; Zhang, K . Scalable manufacturing of a durable, tailorable, and recyclable multifunctional woven thermoelectric textile system . Energy Environ . Sci . , 2023 , 16 ( 10 ), 4334 – 4344 .

Cao, Z. ; Koukharenko, E. ; Tudor, M. J. ; Torah, R. N. ; Beeby, S. P . Screen printed flexible Bi 2 Te 3 -Sb 2 Te 3 based thermoelectric generator . J. Phys. Conf. Ser . , 2013 , 476 ( 1 ), 012031 .

朱国建 , 陈爱英 , 王冉冉 , 孙静 . 用于人体健康监测的可穿戴传感器件研究进展 . 分析化学 , 2022 , 50 ( 11 ), 1673 – 1684 .

ISO 6330:2021. Textiles—Domestic washing and drying procedures for textile testing [S ] . Geneva : International Organization for Standardization , 2021 .

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

碳纤维增强聚醚醚酮复合材料用上浆剂研究进展

磷酰胺成核剂的制备及其对聚丙烯结晶行为的调控机制

机器学习赋能传统高分子实践课程建设与创新——以中空吹塑实验为例

微环境响应多糖基水凝胶在慢性伤口修复中的应用策略

丙烯酸酯改性聚硅氧烷的合成及其紫外光固化性能