摘要:Development-free vapor Photolithography,which was discovered in 1980,is a very unique technology ,however,its mechanism was not clearly understood.A serious of researches on mechanism was carried out by Xiaoyin Hong et al.In this paper the results of the mechanism researches are given.It was proved that the DFVP is based on the photo-induced difference of concentration of etching accelerators in the polymer film, while the traditional photolithography is base on photo-induced difference of solubility of the polymer film. Based on the proposed mechanism some phenomenon involved in DFVC are explained and some improvements have been made.
摘要:Supramolecular liquid crystalline polymers(SLCPs)prepared by self-assembly processes through the formation of intermolecular interactions such as charge transfer,ionic interaction and hydrogen bonding are reviewed,and the progress on device and application of SLCPs as dynamically functional materials is summarized. The future developing directions of SLCPs are also anticipated.
关键词:Liquid crystalline polymer;Supramolecular chemistry;Self-assembly;Dynamically functional materials;Noncovalent bond
摘要:Dendrimers containing azobenzene chromophores is a new kind of functional macromolecules. The study on its synthesis and photoresponsive properties is one of the most active research fields in macromolecular science.This article reviews the synthesis,structure and properties of the dendrimers with photoresponsive azobenzene units in the exterior,interior,or throughout the dendritic architecture.The photoresponsive properties are discussed in detail.
摘要:Polymer nanoparticles hold great potential application in drug delivery system .The advance of polymer nanoparticles for drug delivery system is reviewed in this paper, according to their preparing methods : polymerization of monomers, dispersion of the preformed polymers and self-assembly of amphilic copolymer .
摘要:The preparation methods,properties of polyaniline/inorganic materials composites and polyaniline/ polymer composites are summarized.Some suggestions concerning the development of polyaniline composites are given out.
摘要:Copolymerization Mechanism of Octamethycyclotetrasiloxane and Amio-organsilicone monomer was summarized from the preparation technique in the text .The copolymerization reaction mechanism was emphasized.
关键词:Amio-Polyorganosiloxane;Reaction mechanism;Negative ion copolymerization mechanism;Positive ion copolymerization mechanism
摘要:The current development of catalysts used for syndiotactic polymerization of styrene has been reviewed.This paper focused on some high active catalysts including cyclopentadienyltitanium,indenyltitanium ,fused-ring titanium,fluorinated-titanium and non-metallocene titanium.The different activity of catalysts was explained with the electron and steric effect of substitunents and the stability of active species.
摘要:The structure,morphology and melting behaviors of metallocene-catalyzed branched polyethylene have been studied in this review.The influence of length and content of branches on physics property of branched polyethylene has been discussed.
摘要:Forming mechanism of double percolation phenomenon in electrical conductive composites, distribution of carbon black particles and its application were reviewed.
摘要:In view of the difficulties of practice,a CAI course ware for plastic shaping technique practice was designed.The primary principle,production equipment,process control and corresponding products of various plastic shaping techniques were introduced in this software.By using this CAI course ware,the students can carry out simulative practice and the practice quality can be improved.