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天津纺织工学院,天津,300160
[ "肖长发 1953年12月出生。1982年毕业于上海中国纺织大学化学纤维专业,获工学硕士学位。1987〜1990年在日本留学。现在天津纺织工学院高分子材料与工程教研室工作,副教授。除教学工作外,近年来主要从事有机高性能纤维材料的研制、结构及性能等方面的研究工作,现已发表论文20余篇。" ]
纸质出版日期:1994-12,
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肖长发. 有机高性能纤维材料的轴向压缩变形行为[J]. 高分子通报, 1994,7(4):234-240.
Changfa Xiao. Compressional Behavior of Organic High - performance Fibrous Materials[J]. Polymer Bulletin, 1994,7(4):234-240.
介绍了利用偏光显微镜、扫描电子显微镜及X射线衍射等方法研究具有伸直链结构的有机高性能纤维及膜材料的轴向压缩变形行为。在初级变形阶段,因晶面滑移形成与纤维轴呈一定角度并较有规则的变形带。变形带内大分子受剪切作用发生挫屈或折断。随变形程度增加,变形带堆积厚度以及分布密度增大。如果继续增大变形程度,微原纤维间的相对滑移使材料大分子发生剧烈的侧向位移、高度取向和结晶材料所特有的结构各向异性同性化,试样轴向长度明显缩短,最终导致破坏。
The present work is concerned with the axial compressional behavior of organic high - performance fibers and filmes by means of polarizing optical microscopy
scanning electron microscopy and X - ray diffraction. In the initial stage of compression
kink bands are formed at a proper angle to the draw axis
the molecular chains within the band were broken or bent
that local crystalline slip systems are responsible for the formation of the kink band. With progressive compression
new kink bands were formed near the kink bands that were formed in the initial stage of compression
indicating that compressional stress is concentrated at regions near the kink bands. In the final stage of compression
massive lateral displacement occurred from place to place along fiber axis and the fiber was almost sqeezed out of shape. It can be assumed that intermicrofi- brillar slip plays an important role at the final state of compression.
芳香族聚合物纤维超高分子量聚乙烯膜轴向压缩晶面滑移
Wholly - Aromatic Polymer FibersUltra - High Molecular Weight Polyethylene FilmAxial CompressionCrystalline Slip
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