浏览全部资源
扫码关注微信
北京分子科学国家实验室,高分子化学与物理教育部重点实验室, 北京大学化学与分子工程学院高分子科学与工程系,北京 100871
李子龙,男,博士研究生,研究方向为序列可控高分子设计合成;
*E-mail:zcli@pku.edu.cn.
纸质出版日期:2014-08,
收稿日期:2014-06-02,
修回日期:2014-06-19,
扫 描 看 全 文
李子龙, 王春浩, 杜福胜, 李子臣. 序列可控聚合[J]. 高分子通报, 2014,27(8):13-22.
Zi-long LI, Chun-hao WANG, Fu-sheng DU, Zi-chen LI. Sequence-Regulated Polymerization[J]. Polymer Bulletin, 2014,27(8):13-22.
序列可控聚合是高分子合成方法学的“圣杯",是控制高分子精密结构,进而实现高级功能的重要前提。其最终目标是建立精确控制聚合物单体序列的新方法,深入揭示聚合物结构与性能的关系,从本质上理解单个高分子链内及高分子链间的相互作用,实现单个或几个高分子链的可控链折叠和精密自组装,发展新型功能材料。本文从生物大分子、模板聚合、固相合成、链式聚合以及逐步聚合等方面总结了相关的研究进展,并且就开发精密、高效的序列可控聚合方法以及如何体现序列结构对材料性能的重要影响进行了展望。
Sequence-regulated polymerization is the Holy Grail of polymer science
which paves the way towards hierarchical structures and sophisticated functions. The ultimate goals of sequence-regulated polymerization are to develop new polymerization methods to precisely control the polymer chain microstructures
to get insight on the polymer structure ind property relationship; to deeply understand the intramolecular interaction of a single polymer chain as well as polymer chain interactions
and finally to realize the controlled single polymer chain folding and precise self-assembly of several )olymer chains as well as develop new functional polymeric materials. Recent progress of in biomacromolecule synthesis
templated polymerization
solid-phase synthesis
chain-growth polymerization as well as step-growth polymerization is highlighted. Moreover
we outlook the future direction of ultra-precise and highly efficient sequence regulation nethodology
and the effect of sequenced microstructures on material properties.
序列可控聚合聚合物链精密微结构结构与性能关系
Sequence-regulated polymerizationPrecise microstructure of polymer chainStructure-property relationship
0
浏览量
12
下载量
0
CSCD
关联资源
相关文章
相关作者
相关机构