Study and Application of Antioxidant in Polymer Area
高分子通报2002年15卷第1期 页码:57-66
作者机构:
中国科学院化学研究所,北京 100080
作者简介:
潘江庆(1937—),男,汉族,中国科学院化学所副研究员。1961年毕业于中山大学化学系,高分子专业,同年进入化学所从事高分子材料研究至今。国内外已发表学术论文100篇,参加并出版了三部英文专著。参加的工作有多项获国家级奖励,1993年起,作为访问科学家在国立新加坡大学(National University of Singapdre)从事研究多年。主要领域有功能高分子、复合材料、碳纤维和高分子材料的降解与稳定化。
million tons of polymers are produced worldwide every year
of which a large portion needs various types of stabilizers against degradation for longer service life.Atmospheric oxidation of organic materials including polymer
edible oil
food-stuff
petroleum products and lubricants occurs during their synthesis
production
storage
heat processing and end-use applications.There are many methods to prevent this oxidation
and addition of antioxidants is the most effective and convenient one.In this article we reviewed the recent study advances on acting mechanism of antioxidants
the most effective antioxidant system
optimal molecular weight MW
polymeric antioxidant
polymeric bound antioxidant
multifunctional antioxidant and bio-antioxidant.Attention is drawn to a conclusion that combination of primary antioxidant and secondary antioxidant is the most effective mode for protecting organic materials against atmospheric oxidation.This mode is not likely to be displaced by any other mode in the near future.Hindered phenol antioxidants will displace aromatic amine antioxidants which are toxic.Trends in antioxidant development are that toxic antioxidants will be displaced by non-toxic ones
and more attention will be paid to synthesis of antioxidant with optimal MW
polymeric antioxidant
polymer bound antioxidant
multifunctional antioxidants and bio-antioxidants.Applications of antioxidants in the thermal processing of polymers
lubricants
food and medicines are also disscussed.
关键词
抗氧剂受阻酚芳胺有机物氧化高分子热氧化稳定化
Keywords
AntioxidantHindered phenolAromatic amineOxidation of organic compoundsThermal oxidative stabilisation of polymers