Zu-ren PAN. From Key Problems in PVC Manufacrure to Fundamental Research on Polymer Reaction Engineering[J]. Polymer Bulletin, 2005,18(4):110-115,109. DOI: 10.14028/j.cnki.1003-3726.2005.04.015.
Fundamental research works of polymer reaction engineering rooted from the key problems in PVC manufacture were carried out along with two main aspects concerning with polymer chemistry
technololy and engineering for more than forty years.Polymerization kinetics including rate
degree of polymerization and copolymer composition
microscopic and macroscopic particle formation mechanism
and heat transfer
agitation and mixing
and scale-up technique of reactor were studied in detail.The key problems for developing new types of PVC and related polymers
and for scale-up design of new reactors were easily solved based on the fundamental researches.
关键词
聚氯乙烯聚合动力学成粒机理传热搅拌和混合聚合釜放大技术
Keywords
Poly (vinyl chloride)Polymerization kineticsParticle formation mechanismHeat transferAgitation and mixingScale-up of polymerization reactor