Yong LIU, Yu-zi JIN. Research Progress of Application of Reversible Addition-Fragmentation Chain Transfer Living Radical Polymerization[J]. Polymer Bulletin, 2009,22(6):59-67.
Yong LIU, Yu-zi JIN. Research Progress of Application of Reversible Addition-Fragmentation Chain Transfer Living Radical Polymerization[J]. Polymer Bulletin, 2009,22(6):59-67. DOI: 10.14028/j.cnki.1003-3726.2009.06.005.
可逆加成-断裂链转移(Reversible addition-fragmentation chain transfer , RAFT)自由基聚合是活性自由基聚合领域的一次突破。由于该方法具有适用单体范围广、反应条件温和以及聚合实施方法多样等优点, 已成为一种有效的分子设计和材料设计手段。它不但可实现聚合物链端及链段侧基的功能化和制备特定空间拓扑结构的大分子, 比如嵌段、星型、梳状及链端氨基聚合物等, 还可用于修饰固体材料表面及生物大分子来赋予其特殊的功能。本文综述了RAFT 技术在实际应用中的实施研究进展。
Abstract
Recent developments in the field of controlled/living radical polymerization (CRP) is the presentation of reversible addition-fragmentation chain transfer (RAFT) radical polymerization .Now it has evolved into a powerful synthetic tool for polymerization .RAFT technic
with respect to reaction conditions and monomer class
not only can be applied in the synthesis of well defined homo-
gradient
diblock
triblock
star polymers as well as more complex architectures including microgels and polymer brushes
but also can be used in modification of material surfaces .This review traces of the research progress of application of RAFT living radical polymerization .
关键词
可控自由基聚合可逆加成-断裂链转移(RAFT)分子设计
Keywords
Controlled/living radical polymerizationReversible addition-fragmentation chain transfer (RAFT)Molecular design