Yong-fang LI. High Efficiency Conjugated Polymer Donor and Fullerene Derivative Acceptor Photovoltaic Materials for Polymer Solar Cells[J]. Polymer Bulletin, 2011,24(10):33-49.
Polymer solar cells (PSCs)are composed of a blend film (active layer) of a conjugated polymer donor and a fullerene derivative acceptor sandwiched between a transparent ITO positive electrode and a low workfunction metal negative electrode. PSCs have become the hot research field in recent years
due to their unique advantages of simple fabrication
low cost
light weight and capability to be fabricated into flexible devices. The present research focus is to improve their photovoltaic power conversion efficiency (PCE)
and the key aspects for improving PCE are high efficiency photovoltaic materials. In this paper
I will mainly introduce the recent research progress of Institute of Chemistry
Chinese Academy of Sciences (ICCAS) on the new conjugated polymer donor and fullerene derivative photovoltaic materials
including the donor materials of two-dimensional conjugated polymers with conjugated side chains
conjugated polymers with electron-withdrawing substituents for lower HOMO energy levels
D-A copolymer with broad absorption and lower HOMO energy levels
and the acceptor materials of indene-C
60
bisadduct (ICBA) and indene-C
70
bisadduct. The highest PCE of the PSCs based on the conjugated polymer donor materials reached 7.59 %
which is one of the highest efficiencies reported in literatures so for. The PSCs based on P3HT as donor and our ICBA as acceptor showed PCE higher than 7%
which is the highest efficiency for the PSCs based on P3HT.
关键词
聚合物太阳能电池共轭聚合物光伏材料富勒烯衍生物两维共轭聚合物D-A 共聚物
Keywords
Polymer solar cellsConjugated polymer photovoltaic materialsFullerene derivativesTwo-dimensional conjugated polymersD-A copolymers