At present

one of the most fascinating subjects in areas such as nanoscience and biomimetic chemistry is concerned with the construction of novel complex macromolecular and supramolecular architectures with well defined shapes and functions by using specifically designed organic building blocks. In coil-rod-coil tirblock molecular system

the anisotropic orientation of the rod segments and the repulsion between the covalently connected blocks lead to self-organization into a wide variety of aggregation structures that can be manipulated by variation of coil volume fraction

molecular length

cross-sectional area of coil segment

the side groups in the center of rod segment

as well as the shape of the rod segments. The various parameter influence on self-assembly of coil-rod-coil triblock molecules was summarized in this article

the relationship between these parameters and the construction of the supramolecular structure was discussed

the work was significance of guiding on designing and synthesising the self-assembly molecules in future.