The acrylic resin was prepared by adjusting the content of the hard segment (methyl methacrylate) and the soft segment (ethyl acrylate

butyl acrylate) with the AIBN as initiator by free rae acrylic resin by using the neutralization reaction. Finally

four types of copper acrylate resin were prepardical polymerization

then the copper hydroxide was introduced into the side chain of thed. The structure of the resin was analyzed by IR and GPC

IR validated that the C = C absorption peaks disappeared completely

GPC confirmed that the average molecular weight of the resin is 11000〜13000

indicating that the polymerization reaction was completed; The thermal properties of the resin was studied by DSC and TGA

the glass transition temperature ( T

g

) increased linearly with the increase of the methyl methacrylate content

the thermal stability decreased with the increase of hard segment content. SEM found that the copper ions dispersed uniformly in the resin system

XRD showed that the resin have an amorphous structure. In addition

the four kinds of resin adhesion are excellent

viscosity of resin solution increases modestly with the increase of the hard segment content.