Kadir AYGUL, Awuti TUNISHAGULI, Nurulla ISMAYI. Affect the Performance of the Polymerization Process of Polyaniline[J]. Polymer Bulletin, 2015,28(11):56-63.
Kadir AYGUL, Awuti TUNISHAGULI, Nurulla ISMAYI. Affect the Performance of the Polymerization Process of Polyaniline[J]. Polymer Bulletin, 2015,28(11):56-63. DOI: 10.14028/j.cnki.1003-3726.2015.11.008.
N-dichloro-p-benzoquinone diimine and p-dibromobenzene Grignard reagent using metal Ni (II) complexes as catalyst and through chemical oxidation of aniline respectively. Characterization and performance tests of the copolymers were conducted by Fourier Translation Infrared Spectroscopy (FT-IR)
Ultraviolet and Visible Spectrophotometry (UV-Vis)
Cyclic Votammogram (CV)
charge and discharge analysis
X-ray Diffraction analysis (XRD) and Thermogravimetric Analysis. Results show that the UV-Vis maximum absorption peak of polymer P1 appear at 600nm
while the UV-Vis maximum absorption peak of polymer P2 appear at 443nm. Cyclic Votammogram results indicate that both of the polymers have reversible oxidation-reduction performances
and the p-doped peaks of P1 and P2 appeared at 0.26eV and 0.49eV
respectively.
关键词
聚苯胺金属Ni(II)催化氧化聚合法还原掺杂
Keywords
PolyanilineMetal Ni (II) catalyticOxidative polymerizationReductionDoping