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应用表面与胶体化学教育部重点实验室,陕西师范大学化学化工学院,西安 710062
*E-mail:zhangy@snnu.edu.cn.
纸质出版日期:2016-08-20,
收稿日期:2015-12-10,
修回日期:2016-03-18,
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牛瑞, 王明月, 刘立峰, 张颖. 不同结构形态二氧化硅/高分子复合微凝胶材料制备研究[J]. 高分子通报, 2016,29(8):89-99.
Rui NIU, Ming-yue WANG, Li-feng LIU, Ying ZHANG. Advances in Synthesis of Sensitive Silica/Polymer Composite Microgel Materials with Different Structures[J]. Polymer Bulletin, 2016,29(8):89-99.
牛瑞, 王明月, 刘立峰, 张颖. 不同结构形态二氧化硅/高分子复合微凝胶材料制备研究[J]. 高分子通报, 2016,29(8):89-99. DOI: 10.14028/j.cnki.1003-3726.2016.08.010.
Rui NIU, Ming-yue WANG, Li-feng LIU, Ying ZHANG. Advances in Synthesis of Sensitive Silica/Polymer Composite Microgel Materials with Different Structures[J]. Polymer Bulletin, 2016,29(8):89-99. DOI: 10.14028/j.cnki.1003-3726.2016.08.010.
敏感性二氧化硅/高分子微凝胶复合材料既具有二氧化硅良好的化学稳定性、低毒性和易于功能性,又具有敏感性高分子微凝胶对外界环境(如温度、pH等)的刺激响应特性,因而广泛应用于药物控释、吸附分离、载体和微反应器等重要领域。本文根据二氧化硅和敏感性高分子复合结构的不同,对二氧化硅/高分子核-壳型复合微凝胶、高分子/二氧化硅核-壳型复合微凝胶及杂化网络结构二氧化硅-高分子复合微凝胶等三类复合材料的制备研究进展进行较为详尽地阐述和分析。
Sensitive silica/polymer composite microgel materials not only possess excellent chemical stability
hypotoxicity and easily functionality based on silica (SiO2 ) nanoparticles
but also present the environmental sensitivity to the external environment stimuli (such as temperature
pH
etc. ) inherited from stimuli-responsive polymer microgels. Therefore
this kind of composite materials are widely used in some important fields including drug release
adsorptive separation
carrier
microreactor
etc. According to the structures of sensitive silica/polymer composite materials
this review article will report the progress made in synthesis of three types of composite materials
namely silica/polymer core-shell composite microgels
polymer/silica core-shell composite microgels and hybrid network structure silica/polymer composite microgels.
二氧化硅高分子微凝胶敏感性复合材料
SilicaPolymer microgelsSensitivityComposite materials
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