Meng-ting TAN, Yan SHI, Feng WANG. Progress of RAFT-Mediated Polymerization-induced Self-assembly and the Preparation of Functional Encapsulated Particles[J]. Polymer Bulletin, 2018,31(1):23-37.
Meng-ting TAN, Yan SHI, Feng WANG. Progress of RAFT-Mediated Polymerization-induced Self-assembly and the Preparation of Functional Encapsulated Particles[J]. Polymer Bulletin, 2018,31(1):23-37. DOI: 10.14028/j.cnki.1003-3726.2018.01.003.
polymerization-induced self-assembly( PISA) has been used to prepare block copolymer nano-objects of controllable size
shape
and surface chemistry via reversible addition-fragmentation chain transfer (RAFT) polymerization methods. Some polymer materials with excellent functions were further obtained by functional encapsulation with these copolymer nano-objects. This paper gave a general overview about preparing multiple morphologies of block copolymer aggregates via RAFT-mediated PISA in heterogeneous polymerization system
and introduced the process of morphological development under different polymerization methods
the adapted monomers and the factors influencing the morphological transition. In addition
the advances of PISA in the functional particles encapsulation
the potential applications and limitations of PISA concepts were also presented.
关键词
聚合诱导自组装可控自由基聚合负载功能化非均相聚合
Keywords
Polymerization-induced self-assembly ( PISA)Reversible addition-fragmentation chain transfer (RAFT)Functional encapsulationHeterogeneous polymerization