Miao DU, Li-ping ZHU. Analysis of Chain Polymerization Process Engineering in Teaching "Foundation of Polymerization Reaction Engineering"[J]. Polymer Bulletin, 2018,31(5):105-110.
Miao DU, Li-ping ZHU. Analysis of Chain Polymerization Process Engineering in Teaching "Foundation of Polymerization Reaction Engineering"[J]. Polymer Bulletin, 2018,31(5):105-110. DOI: 10.14028/j.cnki.1003-3726.2018.05.016.
the relationships between active chain concentration ([
P
·]) and conversion (
x
)
conversion and polymerization time (
t
) with or without the quasi-stable state hypothesis were discussed. Under the quasi-stable state
x
~
t
curve
not [
P
·]~
x
curve
is influenced by the operation mode. With the polymerization mechanism of initiator trigger and coupling or disproportionation termination
higher conversion could be gained in batch reactor than that in continuous stirred tank reactor under the same polymerization time. Without the quasi-stable state hypothesis
both [
P
·]~
x
curve and
x
~
t
curve are influenced by the operation mode. With the polymerization mechanism of initiator trigger and no termination
higher conversion could be gained in continuous stirred tank reactor than that in batch reactor under the same polymerization time. We hope that the results could contribute to the teaching of lectures and studying of undergraduates.