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华中科技大学化学与化工学院, 武汉 430074
杨娟(1989-),女,硕士生,主要研究方向为超交联微孔聚合物的合成及应用。E-mail:yangjuan@hust.edu.cn;
*谭必恩(1971-),男,教授,博导,主要研究兴趣集中于纳米材料、微孔聚合物合成及气体储存研究、超临界流体化学、空间有机材料、特种高分子材料及树脂基先进复合材料等领域。E-mail:bien.tan@mail.hust.edu.cn;Tel:027-87558172;Fax:027-87543632.
纸质出版日期:2018-06-20,
收稿日期:2018-01-05,
修回日期:2018-03-04,
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杨娟, 金尚彬, 谭必恩. 编织超交联微孔聚合物的研究进展[J]. 高分子通报, 2018,31(6):9-20.
Juan YANG, Shang-bin JIN, Bi-en TAN. Research Progress in Knitting Hypercrosslinked Microporous Polymers[J]. Polymer Bulletin, 2018,31(6):9-20.
杨娟, 金尚彬, 谭必恩. 编织超交联微孔聚合物的研究进展[J]. 高分子通报, 2018,31(6):9-20. DOI: 10.14028/j.cnki.1003-3726.2018.06.002.
Juan YANG, Shang-bin JIN, Bi-en TAN. Research Progress in Knitting Hypercrosslinked Microporous Polymers[J]. Polymer Bulletin, 2018,31(6):9-20. DOI: 10.14028/j.cnki.1003-3726.2018.06.002.
超交联微孔聚合物因具有比表面积高、合成条件温和、单体来源广泛、催化剂廉价易得等优点而得到广泛关注。近年来,作为一种简单有效的新合成策略,外交联"编织"法成为制备超交联微孔聚合物主要方法之一。该方法可以从低官能度化合物制备得到高比表面积和孔径可调控的超交联聚合物,进一步扩大了构筑单体的选择范围,还可降低副产物的危害,为低成本大规模制备超交联聚合物材料提供了可能。本文对编织超交联聚合物的合成方法进行了总结,并对其在形貌控制中的应用、所得编织微孔聚合物的应用(气体储存和分离、催化、有毒物质吸附、药物控制释放、储能、色谱分离、传感以及碳材料前体等)进行了介绍,最后对外交联"编织"法所面临的问题和挑战、发展前景进行了展望。
Hypercrosslinked microporous polymers (HCPs) have attracted great attention due to their high surface areas
mild synthetic conditions
abundant building blocks
low cost and easily attainable catalysts. In recent years
knitting strategy with external cross-linker has become a primary method for the preparation of HCPs as a sort of simple
effective and new synthetic strategy. HCPs with high surface areas and tunable porous structures can be prepared by knitting low functionality aromatic compounds
which further expands the range of monomer
eliminates the hazards of by-products and provides possibility to produce large-scale and low cost HCPs. In this review
we summarized novel and general synthetic strategies for the design and synthesis of HCPs. The morphology control of HCPs and applications including gas storage and capture
catalysis
removal of pollutants
drug delivery
energy storage
chromatographic separation
sensing and carbon precursor were also discussed. Finally
we talk about the problems and challenges in the future as well as predict the further development of knitting strategy.
编织法外交联超交联微孔聚合物
Knitting strategyExternal crosslinkingHypercrosslinked microporous polymers(HCPs)
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