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1.陕西省大分子重点实验室, 陕西省能源新材料与器件重点实验室, 陕西师范大学材料科学与工程学院, 西安 710062
2.渭南师范学院化学与材料学院, 渭南 714099
*E-mail:jiaxing@snnu.edu.cn.
纸质出版日期:2018-06-20,
收稿日期:2018-01-31,
修回日期:2018-04-24,
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毛娜, 许云峰, 蒋加兴. 共轭微孔聚合物光催化分解水制氢研究进展[J]. 高分子通报, 2018,31(6):215-230.
Na MAO, Yun-feng XU, Jia-xing JIANG. Recent Advances of Conjugated Microporous Polymer Photocatalysts for Hydrogen Evolution[J]. Polymer Bulletin, 2018,31(6):215-230.
毛娜, 许云峰, 蒋加兴. 共轭微孔聚合物光催化分解水制氢研究进展[J]. 高分子通报, 2018,31(6):215-230. DOI: 10.14028/j.cnki.1003-3726.2018.06.019.
Na MAO, Yun-feng XU, Jia-xing JIANG. Recent Advances of Conjugated Microporous Polymer Photocatalysts for Hydrogen Evolution[J]. Polymer Bulletin, 2018,31(6):215-230. DOI: 10.14028/j.cnki.1003-3726.2018.06.019.
氢能开发是未来解决能源危机和环境污染问题的理想途径之一,利用太阳能光催化分解水制氢被认为是一种极具潜力的制氢技术,而开发高效、廉价的实用性新型光催化剂是实现这一技术的关键,成为当前该领域的研究热点。目前,光催化制氢材料主要集中于无机半导体材料如金属氧化物或硫化物等体系,但这些传统的光催化材料存在可见光响应弱、制备条件苛刻及资源短缺等问题。相对于无机半导体光催化剂而言,有机半导体光催化剂具有合成方法多样、易功能化修饰、能带结构和电子结构易调控等诸多优势,使其在光催化制氢领域具有巨大的应用潜力。尤其是近年来发展起来的有机共轭微孔聚合物材料,具有传统共轭聚合物的半导体特性及高比表面积的多孔特性,成为一类新型的有机光催化剂材料,吸引了众多的研究关注。本文主要综述了近年来有机共轭微孔聚合物在光催化制氢领域取得的进展,并对有机聚合物光催化剂面临的挑战和未来发展方向做了综合性概括。
The development of hydrogen energy is one of strategies to solve the problems of energy crisis and environmental pollution. The usage of solar energy to produce hydrogen from water splitting has attracted much attention
in which the key point is to develop efficient and cheap photocatalysts. The current leading photocatalysts for hydrogen evolution are mainly based on inorganic semiconductors such as metal oxide or sulfide
which could absorb UV or visible light to generate electrons and holes. However
most inorganic or metal-based photocatalytic materials suffer from low photocatalytic activity under visible-light
harsh preparation conditions
and the limitation of resource. Organic polymeric photocatalysts have been the subject of intense recent interest due to their diverse synthetic modularity
which allows the fine synthetic control over their chemical structures and electronic properties. In particular
conjugated microporous polymers (CMPs)
as a novel class of organic photocatalysts for hydrogen evolution
have attracted much attention because of their extended π-conjugation along the polymer skeleton and high specific surface area. In this review
a brief summary on the recent development of polymer photocatalysts for hydrogen evolution from water splitting
including linear conjugated polymers
conjugated microporous polymers
and other related porous organic polymers has been made. Some challenges and prospects of organic polymer photocatalysts for photocatalytic hydrogen evolution from water splitting are also envisaged.
共轭微孔聚合物氢有机光催化剂水分解
Conjugated microporous polymerHydrogenOrganic photocatalystWater splitting
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