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1.北京化工大学 机电工程学院,北京 100029
2.北京路德永泰环保科技有限公司,北京 101300
3.北京化工大学 材料科学与工程学院,北京 100029
董大伟(1982-),男,黑龙江肇东人,北京化工大学博士后,研究方向为废轮胎橡胶的再生利用;
*张立群,E-mail: zhanglq@mail.buct.edu.cn.
纸质出版日期:2019-01-20,
收稿日期:2018-11-02,
修回日期:2018-11-15,
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董大伟, 李田田, 董进学, 江宽, 刘双旺, 吴大鸣, 张立群. 废轮胎橡胶粉在非固化橡胶沥青防水涂料中的应用研究[J]. 高分子通报, 2019,32(1):56-63.
Da-wei DONG, Tian-tian LI, Jin-xue DONG, Kuan JIANG, Shuang-wang LIU, Da-ming WU, Li-qun ZHANG. Application of Waste Tire Rubber Powder in Non-curable Rubber Asphalt Waterproof Coating[J]. Polymer Bulletin, 2019,32(1):56-63.
董大伟, 李田田, 董进学, 江宽, 刘双旺, 吴大鸣, 张立群. 废轮胎橡胶粉在非固化橡胶沥青防水涂料中的应用研究[J]. 高分子通报, 2019,32(1):56-63. DOI: 10.14028/j.cnki.1003-3726.2019.01.007.
Da-wei DONG, Tian-tian LI, Jin-xue DONG, Kuan JIANG, Shuang-wang LIU, Da-ming WU, Li-qun ZHANG. Application of Waste Tire Rubber Powder in Non-curable Rubber Asphalt Waterproof Coating[J]. Polymer Bulletin, 2019,32(1):56-63. DOI: 10.14028/j.cnki.1003-3726.2019.01.007.
本文探索了采用橡胶粉制备非固化橡胶沥青防水涂料(非固化涂料)的可行性。结果表明,采用80目橡胶粉可以制备满足JC/T2428-2017要求的非固化涂料。由于橡胶粉交联态属性限制了分子链运动能力,其添加比例较低。为充分实现橡胶粉中的橡胶特点,本文探索了将脱硫橡胶粉用于制备非固化涂料的可行性。结果表明,大比例添加脱硫降解程度(活化度)在50%左右的脱硫胶粉,基本不影响非固化涂料的性能。适宜的配比为(以沥青为100质量份计):15%的脱硫胶粉、30%的增塑剂、9% SBR、2%的温敏触变剂以及60%滑石粉。由于脱硫胶粉中的小分子组分与增塑剂、准线性化大分子橡胶组份以及甲苯不可溶物与SBR作用机理类似,上述共同作用可替代传统方案中部分增塑剂以及SBR,并得到优异的综合物理性能。
This paper explores the feasibility of preparing non-curable rubber modified asphalt waterproofing coating with rubber powder. The results show that 80 mesh rubber powder can be used to prepare non-curable rubber modified asphalt waterproofing coating to meet the requirements of JC/T2428-2017. Because the crosslinking of rubber powder limits the kinematic ability of molecular chain
it can not give full play to the characteristics of linearized rubber. In order to fully realize these characteristics
the feasibility of using reclaimed tire rubber powder to prepare non-curable rubber modified asphalt waterproofing coating was explored. The results showed that the reclaimed rubber powder with the degree of desulfurization degradation (activation degree) of about 50% could be added in large proportion without affecting the non-curing properties. The optimum proportion is 15% reclaimed tire rubber powder
30% plasticizer
9% SBR
2%thermosensitive thixotropic agent and 60% talc powder with 100% asphalt. Because the small molecular components of reclaimed rubber powder are similar to plasticizers
quasi-linear macromolecular rubber components and toluene insoluble substances in the mechanism of action with SBR
the above-mentioned interaction can replace some plasticizers and SBR in the traditional scheme
and obtain excellent comprehensive physical properties.
非固化防水涂料橡胶粉脱硫胶粉
Non-curableWaterproofing coatingRubber powderReclaimed tire rubber powder
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