HU Wen-ying, LIU Tao, WU Qiang-qiang. Preparation and Application of Phenol Electrochemical Sensor Based on Molecularly Imprinted Polymer[J]. Polymer Bulletin, 2022,35(12):129-137.
HU Wen-ying, LIU Tao, WU Qiang-qiang. Preparation and Application of Phenol Electrochemical Sensor Based on Molecularly Imprinted Polymer[J]. Polymer Bulletin, 2022,35(12):129-137. DOI: 10.14028/j.cnki.1003-3726.2022.12.015.
methyl acrylamide as cross-linking agent and azobiisobutyronitrile as initiator
the phenol molecular imprinted polymers were prepared by solution polymerization. Based on self-assembly technology
the adsorption process of polymers on the gold electrode was enhanced by the sensitization of chitosan to prepare phenol molecular blot electrochemical sensors. Scanning electron microscopy results showed the surface of imprinted polymer presented many grooves and many voids. The successful preparation of electrochemical sensor was verified by cyclic voltammetry (CV)and AC impedance (alternating cuncent impedance). By optimizing the experimental conditions
the peak current time was best when the time was 20min. Phenol concentration had a good linear relationship with peak current within the range 6.7×10
-6
~24.6×10
-6
mg/L
and its detection limit was 3.55×10
-9
mg/L. The prepared sensor was used to test the water sample to determine the phenol content