ZHOU Chuang, ZHANG Li, LI Pu-wang, HE Zu-yu, WANG Chao, LIU Yun-hao, SONG Shu-hui, XIE Mu-biao, YANG Zi-ming. Study on Friedel-Crafts Alkylation Reaction of Methyl Eleostearate Catalyzed by UV/Inorganic Acid[J]. Polymer Bulletin, 2022,35(12):154-162.
ZHOU Chuang, ZHANG Li, LI Pu-wang, HE Zu-yu, WANG Chao, LIU Yun-hao, SONG Shu-hui, XIE Mu-biao, YANG Zi-ming. Study on Friedel-Crafts Alkylation Reaction of Methyl Eleostearate Catalyzed by UV/Inorganic Acid[J]. Polymer Bulletin, 2022,35(12):154-162. DOI: 10.14028/j.cnki.1003-3726.2022.12.018.
tung oil-based derivatives were prepared using UV light as the energy source and the inorganic acid as the catalyst. First
methyl eleostearate was prepared via the transesterification reaction between tung oil and methanol
and then reacted with resorcinol to synthesize tung oil-based derivatives (ME-RES) by Friedel-Crafts alkylation reaction under UV light. The structure of the product was also characterized and analyzed by Fourier transform infrared (FT-IR) spectroscopy
ultraviolet and visible (UV-Vis) spectroscopy
nuclear magnetic resonance (NMR) spectroscopy and high performance liquid chromatography-mass spectroscopy (HPLC-MS). Finally
the influence of factors such as catalyst and solvent on the reaction was investigated through a single factor. The research results showed that concentrated sulfuric acid could catalyze the alkylation reaction of methyl eleostearate and resorcinol under the condition of UV light
and the suitable concentration range was 80%-90%
while the ordinary proton acids such as H
3
PO
4
CH
3
COOH could not catalyze the alkylation reaction under UV light. In addition
the research have found that photochemical reactions have the advantages of short reaction time