LIU Wei, LIU Gui-hua, HONG Mei, PAN Yan-xiong, JI Xiang-ling. Progress in Solution Properties of Soluble Polyimides[J]. Polymer Bulletin, 2023,36(8):1076-1089.
LIU Wei, LIU Gui-hua, HONG Mei, PAN Yan-xiong, JI Xiang-ling. Progress in Solution Properties of Soluble Polyimides[J]. Polymer Bulletin, 2023,36(8):1076-1089. DOI: 10.14028/j.cnki.1003-3726.2023.08.012.
foams and has been widely applied in many high-tech fields such as aerospace
liquid crystal display
microelectronics and so on. Among them
the application of PI films is particularly extensive. In the process of preparing PI films from solution
it is very important to control the chain structure of polyimide in the solution which further influences the condensed structure and the properties of the films. Therefore
it is necessary to study the properties of polyimide solutions. The properties of polymer solution include the conformation and flexibility of polymer chain in solution
the molecular parameters related to the chain conformation and their scaling relationships
and the factors affecting the chain conformation. In this paper
recent progress on the solution properties of soluble polyimide was summarized including the chain conformation
basic molecular parameters and their scaling relationships
the effects of structural factors and external conditions (temperature
etc.
) on the chain flexibility of some soluble polyimides in different solvents. The future development of the research on the solution properties of soluble polyimide is also proposed.