聚2,7-二(氮咔唑基)-9,9-二甲基芴合成及CO<sub>2</sub>吸附性能应用

许辉; 方柳亚; 段小鹏; 王庆; 樊治海; 白小亮; 蔡克

doi:10.14028/j.cnki.1003-3726.2024.23.189

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聚2,7-二(氮咔唑基)-9,9-二甲基芴合成及CO₂吸附性能应用

研究论文 | 更新时间：2024-01-11

- 聚2,7-二(氮咔唑基)-9,9-二甲基芴合成及CO₂吸附性能应用
- Synthesis and CO₂ Adsorption of 9,9'-(9,9-Dimethyl-9H-fluorene-2,7-diyl)bis(9H-carbazole) Polymer
- 高分子通报 2024年37卷第1期页码：89-95
- 作者机构：
  
  1..中国石油集团工程材料研究院有限公司，西安　710077
  2..长庆油田公司第六采气厂，西安　710018
  3..长庆油田公司第一采油厂，延安　716009
- 作者简介：
  
  *许辉，E-mail: xuhui5@cnpc.com.cn
- 基金信息：
- DOI：10.14028/j.cnki.1003-3726.2024.23.189
  中图分类号：
- 纸质出版日期：2024-01-20，
  
  收稿日期：2023-06-03，
  
  录用日期：2023-06-29
- 稿件说明：
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许辉, 方柳亚, 段小鹏, 王庆, 樊治海, 白小亮, 蔡克.聚2,7-二(氮咔唑基)-9,9-二甲基芴合成及CO₂吸附性能应用. 高分子通报, 2024, 37(1), 89–95

Xu, H.; Fang, L. Y.; Duan, X. P.; Wang, Q.; Fan, Z. H.; Bai, X. L.; Cai, K. Synthesis and CO₂ adsorption of 9,9'-(9,9-dimethyl-9H-fluorene-2,7-diyl)bis(9H-carbazole) polymer. Polym. Bull. (in Chinese), 2024, 37(1), 89–95
许辉, 方柳亚, 段小鹏, 王庆, 樊治海, 白小亮, 蔡克.聚2,7-二(氮咔唑基)-9,9-二甲基芴合成及CO₂吸附性能应用. 高分子通报, 2024, 37(1), 89–95 DOI： 10.14028/j.cnki.1003-3726.2024.23.189.

Xu, H.; Fang, L. Y.; Duan, X. P.; Wang, Q.; Fan, Z. H.; Bai, X. L.; Cai, K. Synthesis and CO₂ adsorption of 9,9'-(9,9-dimethyl-9H-fluorene-2,7-diyl)bis(9H-carbazole) polymer. Polym. Bull. (in Chinese), 2024, 37(1), 89–95 DOI： 10.14028/j.cnki.1003-3726.2024.23.189.

摘要

报道一种新的、高效的方法合成2

7-二(氮咔唑基)-9

9-二甲基芴(9

9'-(9

9-dimethyl-9

-fluorene-2

7-diyl)bis(9

-carbazole)，MFC)，并以该物质为聚合单体，以FeCl

为促进剂，在室温下聚合得到聚2

7-二(氮咔唑基)-9

9-二甲基芴(MFC-CMP-1)。之后对该聚合物进行性质表征，包括形貌、热稳定性、孔结构等，并进行多种气体(N

、CH

、CO

)的吸附试验。结果表明该材料对CO

表现出良好的吸附性能，其吸附量达到50.4 cm

/g (0.1 MPa和273 K条件下)，且吸附选择性良好。这对于设计并合成高效的气体吸附剂、二氧化碳捕集利用和储存相关应用，具有一定的参考价值。

Abstract

9'-(9

9-Dimethyl-9

-fluorene-2

7-diyl)bis(9

-carbazole) (MFC) was synthesized with a new and efficient strategy. Then

the porous organic polymer (MFC-CMP-1) with FeCl

as the accelerator was obtained by self-polymerization at room temperature with MFC as the reaction monomer. The characteristics of MFC-CMP-1 (including morphology

thermostability and pore structure) were disclosed and used as an adsorbent to implement the gas (N

) capture tests. We were delighted to find that MFC-CMP-1 displayed excellent adsorptive capacity (50.4 cm

/g under 0.1 MPa

273 K) and selectivity for CO

. This research could provide a rational principle for designing

synthesis of efficient adsorbent

and is benefit for the development of carbon capture

utilization and storage.

关键词

多孔有机聚合物咔唑基二氧化碳吸附

Keywords

Porous organic polymerCarbazolylCO2 adsorption

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聚2,7-二(氮咔唑基)-9,9-二甲基芴合成及CO2吸附性能应用

Synthesis and CO2 Adsorption of 9,9'-(9,9-Dimethyl-9H-fluorene-2,7-diyl)bis(9H-carbazole) Polymer

DOI：10.14028/j.cnki.1003-3726.2024.23.189

摘要

Abstract

关键词

Keywords

references

聚2,7-二(氮咔唑基)-9,9-二甲基芴合成及CO₂吸附性能应用

Synthesis and CO₂ Adsorption of 9,9'-(9,9-Dimethyl-9H-fluorene-2,7-diyl)bis(9H-carbazole) Polymer