功能性非异氰酸酯聚氨酯的研究进展

张嘉滢; 宋丹青; 刘义; 郑柳春

doi:10.14028/j.cnki.1003-3726.2024.24.199

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功能性非异氰酸酯聚氨酯的研究进展

综述 | 更新时间：2024-12-12

- 功能性非异氰酸酯聚氨酯的研究进展
- Research Progress of Functional Non-isocyanate Polyurethane
- 高分子通报 2024年37卷第12期页码：1731-1739
- 作者机构：
  
  1.天津工业大学纺织科学与工程学院和省部共建分离膜与膜过程国家重点实验室，天津 300387
  2.新疆大学化工学院，乌鲁木齐 830046
  3.沧州市天津工业大学研究院，沧州 610000
- 作者简介：
  
  *郑柳春，E-mail: liuchunzheng@tiangong.edu.cn
- 基金信息：
  
  国家自然科学基金面上项目(52173009);沧州市天津工业大学研究院项目(TGCYY-F-0105);沧州市重大研发计划项目(222104010);天津市科技计划项目(23JCZDJC00030;24JRRCRC00040);河北省科技计划项目(246Z1205G)
- DOI：10.14028/j.cnki.1003-3726.2024.24.199
  中图分类号：
- 纸质出版日期：2024-12-20，
  
  网络出版日期：2024-09-12，
  
  收稿日期：2024-07-06，
  
  录用日期：2024-08-23
- 稿件说明：
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张嘉滢, 宋丹青, 刘义, 郑柳春. 功能性非异氰酸酯聚氨酯的研究进展. 高分子通报, 2024, 37(12), 1731–1739

Zhang, J. Y.; Song, D. Q.; Liu, Y.; Zheng, L. C. Research progress of functional non-isocyanate polyurethane. Polym. Bull. (in Chinese), 2024, 37(12), 1731–1739
张嘉滢, 宋丹青, 刘义, 郑柳春. 功能性非异氰酸酯聚氨酯的研究进展. 高分子通报, 2024, 37(12), 1731–1739 DOI： 10.14028/j.cnki.1003-3726.2024.24.199.

Zhang, J. Y.; Song, D. Q.; Liu, Y.; Zheng, L. C. Research progress of functional non-isocyanate polyurethane. Polym. Bull. (in Chinese), 2024, 37(12), 1731–1739 DOI： 10.14028/j.cnki.1003-3726.2024.24.199.

摘要

聚氨酯综合性能优异

是日常生活和工业中最常用的聚合物材料之一。传统的聚氨酯主要是由多元醇和剧毒的二异氰酸酯或多异氰酸酯的反应来制备。在当前可持续发展的背景下

非异氰酸酯路线合成功能性聚氨酯因制备过程中不使用有毒的异氰酸酯原料

同时又能够满足市场多样化和人们日益增长的功能需求而备受重视。本综述总结了具有应用前景的非异氰酸酯路线制备聚氨酯

详细介绍了以环碳酸酯和碳酸二甲酯为原料的反应路线及其优缺点

并对功能性非异氰酸酯聚氨酯在自修复、形状记忆、可再加工和可粘接性等功能领域的应用研究进展进行了详细探讨，最后对其未来发展方向和趋势进行了展望。

Abstract

Polyurethanes are among the most commonly used polymeric materials in daily life and industry due to their excellent combined properties. Conventional polyurethanes are mainly prepared by the reaction of polyols and highly toxic diisocyanates or polyisocyanates. In the current context of sustainable development

functional non-isocyanate polyurethanes are highly valued because they are prepared without the use of toxic isocyanate raw materials

and at the same time

they can meet the growing demand and market variety. In this review

the preparation routes of non-isocyanate polyurethanes with application prospects were summarized

and reaction routes based on cyclic carbonate and dimethyl carbonate

as well as their advantages and disadvantages

were discussed in detail. The application progress of functional non-isocyanate polyurethanes in fields of self-healing materials

shape memory materials

reprocessable materials and adhesion was also discussed in detail

and the future development direction and trend were prospected.

关键词

非异氰酸酯聚氨酯功能性环境友好

Keywords

Non-isocyanatePolyurethaneFunctionalityEnvironmentally friendly

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