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北京化工大学材料科学与工程学院,北京,100029
[ "杨万泰 男,41岁,教授,博导。1982毕业于清华大学化工系高分子化工专业,1985年3月在北京化工大学高分子系取得硕士学位后留校工作,1996年4月在瑞典皇家理工学院取得工学博士学位。目前正在从事的研究方向:可控性表面接枝聚合的理论及应用,阴离子和自由基活性聚合,高分子材料的表面改性。拥有3项发明专利,发表论文30多篇。" ]
纸质出版日期:1999-03,
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杨万泰, 尹梅贞, 邓建元, 杜久明. 表面光接枝原理、方法及应用前景[J]. 高分子通报, 1999,12(1):60-65,84.
Wantai Yang, Meizhen Yin, Jianyuan Deng, Jiuming Du. Principle,Process and Application of Surface Photografting Polymerization[J]. Polymer Bulletin, 1999,12(1):60-65,84.
杨万泰, 尹梅贞, 邓建元, 杜久明. 表面光接枝原理、方法及应用前景[J]. 高分子通报, 1999,12(1):60-65,84. DOI: 10.14028/j.cnki.1003-3726.1999.01.009.
Wantai Yang, Meizhen Yin, Jianyuan Deng, Jiuming Du. Principle,Process and Application of Surface Photografting Polymerization[J]. Polymer Bulletin, 1999,12(1):60-65,84. DOI: 10.14028/j.cnki.1003-3726.1999.01.009.
介绍了表面光接枝的原理、方法和应用前景。表面光接枝主要是用芳酮引发有机材料产生表面自由基,从而引发单体聚合生成表面接枝链。实施方法有气相法、液相法和连续液相法。表面光接枝应用领域广泛,可用于聚合材料的表面改性以及表面功能化。
Surface photografting polymerization (SPGP) may be intiated by the photoredution reation of an aromatic ketone with a surface H-donors
the chain transfer of a free radical to the surface of organic materials
as well as the fragmentation of a special photo-sensitive group on the surface of materials.SPGP may be conducted by a vapor phase process
a liquid phase process or a bulk phase process.The previous applications of SPGP are surface modification of organic materials
especially polyolefins.The main properties modified by SPGP are adhesiveness
printability
paintability
dyeability
anti-fogging properties
gloss
anti-static properties
lubrication
anti-staining properties
bio-compatibility
heat sealability
and so on.In recent years
extensive researches have been reported for the functionalization of a polymer surface
e.g.
the preparation of separation membrane
polymer-supported catalysts
reagents
ligands for absorption of metal ions
as well as polymer forming method.
表面光接枝有机材料表面改性表面功能化
Surface photografting polymerizationOrganic materalSurface modificationFunctionalization of a polymer surface
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