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1.北京航空材料研究院先进复合材料国防科技重点实验室,北京 100095
2.上海交通大学化学化工学院,上海 200240
王克俭(1971-),男,博士,主要从事聚合物及其先进复合材料的制备、加工成型技术和原理研究。
纸质出版日期:2003-02,
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王克俭, 周持兴. 考虑壁面滑移的Z-W 流变模型及其应用[J]. 高分子通报, 2003,16(1):8-17.
Ke-jian WANG, Chi-xing ZHOU. Z-W Rheological Model for Polymer Melt Considering Wall Slip and its Applications[J]. Polymer Bulletin, 2003,16(1):8-17.
王克俭, 周持兴. 考虑壁面滑移的Z-W 流变模型及其应用[J]. 高分子通报, 2003,16(1):8-17. DOI: 10.14028/j.cnki.1003-3726.2003.01.002.
Ke-jian WANG, Chi-xing ZHOU. Z-W Rheological Model for Polymer Melt Considering Wall Slip and its Applications[J]. Polymer Bulletin, 2003,16(1):8-17. DOI: 10.14028/j.cnki.1003-3726.2003.01.002.
总结了聚合物熔体在剪切流场壁面滑移研究的成果
提出了Z-W 模型的物理概念。该模型考虑了界面分子链和固体壁面间解吸-吸附而发生的滑移、界面分子链和内部分子链间解缠-重新缠结而发生的表观滑移以及变形摩擦滑移。在稳态简单剪切流动过程
模型可以化简为应力和应变的二次微分方程
说明了壁面滑移来源于Cohesive 滑移和Adhesive 滑移两部分。对于自激振荡相关的多重内振荡和多重外振荡进行了归纳
应用统一模型定性地解释了毛细管实验中剪切应力的非线性、瞬态自激振荡、滑-粘转换和鲨鱼皮等现象。在聚合物熔体振动剪切流动(LAOS)中
统一模型可以简化为杜芬方程。通过模拟发现
该模型可以解释小应变振幅下振动剪切时的线性流变行为和在大振幅振动流动中的复杂非线性行为。非线性行为与熔体粘弹性以及近壁面界面层的性质有关。统一模型在特殊情况下还可以简化Joshi 模型、结构网络模型、Hatzikiriakos 或等效的 Graham 模型。可见
Z-W 模型内涵比较丰富、适用面较广;也从一个侧面说明该模型具有相当的合理性。
This paper sums the study results on wall slip of polymer melt in shear flow
which leads to the physical meaning of the developed Z-W model. In the model
it was realized that there was interfacial layer at the wall
real wall slip occurred at the wall interface through adsorbing-desorbing; apparent slip occurred in interfacial layer through disentanglement-reentanglement. On the other hand
the interfacial molecules were confined with different dynamics with that of internal melt; there is elastic tension between bulk chains and interfacial ones. Z-W model reduces to one second order differential equation in simple shear flow. This model first quantitatively shows general wall slip contains adhesive slip and cohesive slip as well as elastic deformation slip. The self-oscillation in capillary extrusion was reviewed. It was frist time to propose the definitions of multiple internal self-oscillation and multiple external self-oscillation. The simplified Z-W model qualitativedly explained such nonlinear flow phenomena as the non-linearity of shear stress
the transient self-oscillation in pressure
the stick-slip transtition and sharkskin features in capillary rheometry. The Z-W model was reduced to a
Duffing
equation to show linearity in small amplitude oscillatory shear and complex nonlinearity at large amplitude. The complexity changes with viscoelaticty of polymer melt and vibration amplitude or frequency. The Z-W model also reduces to the published Josh'is model
dynamical network model or the model by Hatzikirizkos and the model by Graham under special conditions. In all
Z-W model was abundant in usage with certain rationality.
聚合物熔体壁面滑移自激振荡振动剪切流动Z-W 模型
Polymer meltWall slipSelf-oscillationOscillatory shearZ-W model
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