介绍了可逆加成-断裂链转移(Reversible addition-fragmentation chain transfer
RAFT)活性自由基聚合的反应机理、聚合动力学和特点
对RAFT试剂的选择和制备作了简要介绍
并综述了RAFT聚合的发展动态及应用状况。
Abstract
In this paper
the mechanism
kinetics and characteristics of the living radical polymerization with reversible addition-fragmentation chain transfer (RAFT) are reviewed in detail. The principles of selecting a proper RAFT agent for a given polymerization
and the synthesis process of the agent are presented briefly. Additionally
the development and application of the RAFT polymerization were summarized.
关键词
活性自由基聚合双硫酯加成-断裂链转移休眠种
Keywords
Living radical polymerizationDithioesterAddition-fragmentation chain transferDormant species