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1..郑州大学化学系,郑州 450052
2..武汉大学 化学与分子科学学院,武汉 430072
郑金云( 1977-) , 女, 郑州大学, 博士, 主要从事有机光电材料和化学生物学研究。
纸质出版日期:2005-06,
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郑金云, 徐占辉, 冯祥明, 詹才茂. 以氧化偶联聚合法制备主链含香豆素的颜色可调发光共聚物[J]. 高分子通报, 2005,18(3):82-88.
Jin-yun ZHENG, Zhan-hui XU, Xiang-ming FENG, Cai-mao ZHAN. The Color-tunable Light Emitting Copolymers Contained Coumarin in the Main Chain Prepared by Oxidative-coupling Copolymerization[J]. Polymer Bulletin, 2005,18(3):82-88.
郑金云, 徐占辉, 冯祥明, 詹才茂. 以氧化偶联聚合法制备主链含香豆素的颜色可调发光共聚物[J]. 高分子通报, 2005,18(3):82-88. DOI: 10.14028/j.cnki.1003-3726.2005.03.012.
Jin-yun ZHENG, Zhan-hui XU, Xiang-ming FENG, Cai-mao ZHAN. The Color-tunable Light Emitting Copolymers Contained Coumarin in the Main Chain Prepared by Oxidative-coupling Copolymerization[J]. Polymer Bulletin, 2005,18(3):82-88. DOI: 10.14028/j.cnki.1003-3726.2005.03.012.
用氧化偶联共聚合方法合成了几种主链上含香豆素或香豆素1 的共聚物。用红外光谱和核磁共振氢谱表征了共聚物的结构。共聚物的结构均为非晶态, 并且呈现良好的热稳定性, 用紫外-可见光谱表征了共聚物的吸收特征。共聚物的荧光光谱表明, 通过含香豆素的共聚物中两单体的不同组成可呈现蓝光、绿光、黄光和红光发射, 发光波长几乎覆盖了整个可见光区, 说明含有香豆素的共聚物可以成为颜色可调的发光聚合物。
The copolymers incorporated coumarin with triphenylamine
butyloxybenzene
stilbene
9
9-di ( 2- ethylhexyl) fluorene
1
2
4
5-tetramethylbenzene and β-methoxynaphthalene prepared by oxidative coupling copolymerization.The structure of polymers was characterized by 1H NMR and FT-IR .The copolymers are all amorphous and have good thermal stability .The electrochemical behaviors of the polymers were investigated by cyclic voltammetry .From the electrochemistry and UV-Vis spectroscopy
the HOMO and LUMO energy level of the polymers were calculated .The absorbance of the polymers were characterized by UV-Vis spectroscopy .The fluorescence spectra of polymers in chloroform solution display that the copolymer of coumarin and triphenylamine is blue-light emitting ;the copolymer of coumarin and dialkyloxyl benzene
and the copolymer of coumarin and tetramethylbenzene are green-light emitting ;the copolymer of coumarin and stilbene is yellow-green or orange light emitting ;and the copolymer of coumarin and β-methoxynaphthalene is red light emitting materials respectively .On the other hand
the copolymers contained coumarin 1 display blue and orange light emitting .In a word
the copolymers contained coumarin display blue
green and red light emitting .Hence it is possible to tune the emission of the copolymers from blue to red by changing the moieties .
氧化偶联共聚合香豆素发光颜色可调
Oxidative coupling copolymerizationCoumarinLight emittingColor-tunable
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