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教育部可控化学反应科学与技术基础重点实验室材料科学与工程学院北京化工大学,北京 100029
刘莲英(1969-),女,湖北省麻城市人,博士,主要从事高分子化学合成研究;
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纸质出版日期:2006-08,
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刘莲英, 孙玉凤, 何辰凤, 杨万泰. 溶液聚合制备微凝胶[J]. 高分子通报, 2006,19(8):52-57.
Lian-ying LIU, Yu-feng SUN, Chen-feng HE, Wan-tai YANG. The Synthesis of Microgels in Solution[J]. Polymer Bulletin, 2006,19(8):52-57.
刘莲英, 孙玉凤, 何辰凤, 杨万泰. 溶液聚合制备微凝胶[J]. 高分子通报, 2006,19(8):52-57. DOI: 10.14028/j.cnki.1003-3726.2006.08.008.
Lian-ying LIU, Yu-feng SUN, Chen-feng HE, Wan-tai YANG. The Synthesis of Microgels in Solution[J]. Polymer Bulletin, 2006,19(8):52-57. DOI: 10.14028/j.cnki.1003-3726.2006.08.008.
溶液聚合制备微凝胶一般是在极稀溶液中进行
为突破这一限制
研究者们进行了多方面的尝试。本文主要从小分子单体溶液聚合、大分子单体溶液聚合及聚合物溶液交联三方面概括介绍了近年来溶液聚合制备微凝胶的研究状况
展望了溶液聚合制备微凝胶的研究发展前景。
Synthesizing microgels in solution is typically characterized with very low initial monomer concentration and quite incomplete conversion
which are disadvantageous to practice. In order to overcome these shortcomings
various attempts have been made in recent years. In this review
the latest investigations on the synthesis of microgels through polymerization of monomer or macromonomer in a concentrated solution
or cross-linking linear macromolecules directly in solution were overviewed and the research work need to be done in future was discussed.
溶液聚合微凝胶制备
SolutionMicrogelSynthesis
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