Mei-shun LI, Zai-jun LU, Ying LIU. Progress in the Self-Assembled Morphologies of the Block Copolymers in Bulk[J]. Polymer Bulletin, 2007,20(11):6-16. DOI: 10.14028/j.cnki.1003-3726.2007.11.002.
A series of morphologies based on the self-assembly of diblock and triblock copolymers in the bulk are summarized in this article.They include (1) the gyriod morphologies formed from diblock copolymers
(2) some morphologies formed from triblock copolymers
such as spherical domains in a CsCl-type structure
cocentric spherical domains in the bcc structure
lamella-sphere
cylinder-sphere
lamella-cylinder
coaxial cylinder
cylindrical domains in a hexagonal lattice structure
lamella-cylinder
lamella-cylinder-Ⅱ
ordered tricontinuous doublediamond
core-shell double gyroid
lamellar
(3) some complex morphologies
such as mushroom
sphere on sphere
knitting-pattern
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their advance in the future was also introduced briefly.