Jin-ming ZHANG, Yu-xia LÜ, Nan LUO, Jin WU, Jian YU, Jia-song HE, Jun ZHANG. Application Research Progress of Ionic Liquids in Cellulose Chemistry[J]. Polymer Bulletin, 2011,24(10):138-153.
Jin-ming ZHANG, Yu-xia LÜ, Nan LUO, Jin WU, Jian YU, Jia-song HE, Jun ZHANG. Application Research Progress of Ionic Liquids in Cellulose Chemistry[J]. Polymer Bulletin, 2011,24(10):138-153. DOI: 10.14028/j.cnki.1003-3726.2011.10.007.
cellulose has many attractive properties such as renew ability
biodegradability
biocompatibility
and bro ad chemical-modifying capacity. Cellulose has been considered as the sustainable raw material of energy and chemical engineering in the future. However
because of the well-developed intra- and intermolecular hydrogen bonding network
cellulose is unmeltable and insoluble in water or conventional organic solvents
which limits its wide utilization. More recently
it is found that certain ionic liquids (ILs) have excellent dissolving capability for cellulose
which provids a new and versatile plat form for cellulose processing and derivatization. A series of biopolymer-based materials
biomass energy
platform chemicals
and so on
have been produced with the aid of ILs. Based on about 210 relevant papers published during the past 10 years
this review article highlights recent progress in the field of dissolution
regeneration
derivatization
extraction and conversion of cellulose with ILs. In additon
a perspective on ILs application in cellulose chemistry in the future is briefly discussed. It is hoped that this review work will stimulate research and collaborations that will lead to significant progress in this area.