
浏览全部资源
扫码关注微信
1.辽宁工程技术大学 力学与工程学院,阜新 123000
2.辽宁工程技术大学 土木与工程学院,阜新 123000
*E-mail:WB-An1992@163.com.
纸质出版日期:2018-03-20,
收稿日期:2017-10-19,
修回日期:2017-12-09,
扫 描 看 全 文
安文博, 王来贵, 刘向峰, 潘纪伟, 李喜林. 基于FTIR和XRD法分析阜新长焰煤结构特征[J]. 高分子通报, 2018,31(3):67-74.
Wen-bo AN, Lai-gui WANG, Xiang-feng LIU, Ji-wei PAN, Xi-lin LI. Analysis the Structural Characteristics of Fuxin Long Flame Coal Based on FTIR and XRD Experiments[J]. Polymer Bulletin, 2018,31(3):67-74.
安文博, 王来贵, 刘向峰, 潘纪伟, 李喜林. 基于FTIR和XRD法分析阜新长焰煤结构特征[J]. 高分子通报, 2018,31(3):67-74. DOI: 10.14028/j.cnki.1003-3726.2018.03.009.
Wen-bo AN, Lai-gui WANG, Xiang-feng LIU, Ji-wei PAN, Xi-lin LI. Analysis the Structural Characteristics of Fuxin Long Flame Coal Based on FTIR and XRD Experiments[J]. Polymer Bulletin, 2018,31(3):67-74. DOI: 10.14028/j.cnki.1003-3726.2018.03.009.
为了研究阜新长焰煤的大分子结构,通过测定12个煤样品的工业分析和元素分析,选取最接近平均值的煤样CYM-9作为实验样品,采用傅里叶红外光谱(FTIR)、X射线衍射(XRD)和单轴压缩实验对煤样进行研究,通过与抚顺长焰煤结构特征进行对比,进一步分析煤的微晶结构参数及其力学特性。研究结果表明: CYM-9煤样的基本结构特征参数芳氢率(f
ar
H
)为0. 47,氢碳原子比(H/C)为0. 858 ,芳碳率(f
ar
C
)为0. 747,脂肪烃支链长度(CH
3
/CH
2
)为0. 617。与抚顺长焰煤结构相比,其芳碳率较大,芳香核缩合程度较大,芳香结构单元排列秩序较规则;煤样XRD图谱具有002峰和100峰两条明显的峰,层间距(d
002
)为0. 3816nm,层片堆砌高度(L
c
)为1.2462nm,层片直径(L
a
)为1. 0136nm,芳香堆砌层数(N)为4.26 ;煤样的平均峰值强度为 9. 24MPa,达到峰值强度时平均应变值为23. 58 × 10
-3
,平均弹性模量为405MPa。
In order to study the macromolecule structure of Fuxin long flame coal
the CYM-9 coal sample which is closest to the average value was selected as the experimental sample by measuring the industrial analysis and elemental analysis of 12 coal samples
the Fourier transform infrared spectroscopy (FTIR)
X-ray diffraction (XRD) and uniaxial compression experiments were used to study coal samples
the microcrystalline structure parameters and mechanical properties of coal were further analyzed by comparing with the characteristics of Fushun long flame coal. The results show that the basic structure parameters of CYM-9 coal sample were as follows : aromatic hydrogen ratio (
http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=33811886&type=
http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=33811888&type=
http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=33811887&type=
) was 0.47
hydrogen/atomic ratio ( H/C) was 0.858
aromatic carbon ratio (
http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=33811890&type=
http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=33811897&type=
http://html.publish.founderss.cn/rc-pub/api/common/picture?pictureId=33811893&type=
) was 0.747
aliphatic hydrocarbon branch length (CH
3
/CH
2
) was 0. 617
compared with Fushun long flame coal structure
its aromatic carbon ratio was larger
aromatic nucleus condensation degree was bigger
aromatic structure unit arrangement order was more regular;The XRD pattern pf coal samples had two peaks with 002 peak and 100 peak
the layer spacing(d
002
) was 0. 3816 nm
the stacking height (L
c
) was 1. 2462 nm
the layer diameter (L
a
) was 1. 0136 nm
and the number of aromatic piles (N) was 4. 26; The average peak strength of the coal sample was 9. 24MPa
the average strain value was 23. 58× 10
-3
and the average elastic modulus was 405MPa.
阜新长焰煤X射线衍射傅里叶红外光谱煤大分子结构
Fuxin long flame coalX-ray diffractionFourier transform infrared spectroscopyCoal macromolecule structure
0
浏览量
10
下载量
9
CSCD
关联资源
相关文章
相关作者
相关机构
京公网安备11010802024621