Zhi-e ZHANG, Hui-feng ZHANG, Gen-zhu LEI, Ming-yue MA, Shuang-quan LIAO. Changes of Components and Structure of Natural Rubber Latex in the Preparation Process of Centrifugal Concentrated Latex Production[J]. Polymer Bulletin, 2018,31(7):74-81.
Zhi-e ZHANG, Hui-feng ZHANG, Gen-zhu LEI, Ming-yue MA, Shuang-quan LIAO. Changes of Components and Structure of Natural Rubber Latex in the Preparation Process of Centrifugal Concentrated Latex Production[J]. Polymer Bulletin, 2018,31(7):74-81. DOI: 10.14028/j.cnki.1003-3726.2018.07.009.
Centrifugation is an important method for producing the concentrated natural rubber latex (NRL) in the current industrial production. The aims of this project are to investigate the change of the components and structure of natural rubber latex in the preparation process of centrifugal concentrated latex production
including the rubber hydrocarbon
protein
lipid
acetone extract (AE)
water extract
ash of NRL by bromination
Kjeldahl determination
extraction
etc; and particle morphology
size
molecular weight (Mw) and crosslinking network of NR by high resolution transmission electron microscope (HRTEM)
Melvin granulometer
gel permeation chromatography (GPC) and nuclear magnetic resonance crosslink density meter. The result of research shown that all of the components and structure didn't change significantly in the process of clarifying and adjusting. While
with the contents of rubber hydrocarbon
lipid and AE
the contents of protein
water extract and ash decreased in the the centrifugating process. Furthermore
M_w and crosslink density both increased. According to the obtained results
the centrifugating is the key process for the components and structure of natural rubber latex in the preparation process of centrifugal concentrated latex production. And the particle morphology
size
Mw and crosslink structure were influenced by the changes of protein and lipid.