silica sol hybrid was synthesized by the hydrolysis reaction of ethyl silicate(TEOS) at 25℃ under alkaline conditions.Then a series of modified epoxy resins were successfully prepared by using the silica sol hybrid. IR spectrum
epoxy value indicated that the silica sol hybrid is incorporated into epoxy resin. The modified epoxy resin was cured with isophorone diamine (IPDA)
Then investigated the cured materials via measuring the flame retardancy
glass transition temperature (
T
g
)
thermal stability
tensile strength and elongation
microstructure of the cured materials
The effects of chemical modification
physical mixing and the content of the TOES on the properties of the composites were discussed. The results show that the modified epoxy resin obtained by chemical reaction has better performance. The limiting oxygen index and thermal stability of the cured product are obviously higher than that of pure epoxy resin
and the tensile strength and other mechanical properties have been greatly improved
which achieved that the flame retardant
heat resistance and mechanical properties of the epoxy materials were increased at the same time.