GAO Jia-lei, LUO Zhi, SONG Hong-zan, LI Qian, LI Hua-yi, HU You-liang. Progress of Transition Metal Catalyzed Non-alternating Ethylene/Carbon Monoxide Copolymerization[J]. Polymer Bulletin, 2023,36(3):273-281.
GAO Jia-lei, LUO Zhi, SONG Hong-zan, LI Qian, LI Hua-yi, HU You-liang. Progress of Transition Metal Catalyzed Non-alternating Ethylene/Carbon Monoxide Copolymerization[J]. Polymer Bulletin, 2023,36(3):273-281. DOI: 10.14028/j.cnki.1003-3726.2023.03.001.
Due to the high melting point and poor solubility of ethylene/carbon monoxide alternating copolymerization products
there are great difficulties in material processing and application. The catalyst design can realize the non-alternating copolymerization of ethylene/carbon monoxide
reduce the carbonyl content in the copolymer and improve the processability of the material. This paper reviews the progress of neutral transition metal catalysts
cationic transition metal catalysts and metal carbonyl compounds in the non-alternating copolymerization of ethylene and carbon monoxide. Finally
the research of new photodegradable plastics is prospected.
关键词
乙烯/一氧化碳共聚过渡金属催化非交替聚酮可光降解塑料
Keywords
Ethylene/Carbon monoxide copolymerizationTransition metal catalystsNon-alternating polyketonePhotodegradable plastics