ZHAO Wei-yuan, CHAI Jia-hou, TANG Wei-ye, WANG Sa-sa, LI You, CHEN Ying. Effects of Pre-stretching Treatment on Conductive and Sensing Properties of Elastic Polypyrrole Filaments[J]. Polymer Bulletin, 2023,36(10):1330-1336.
ZHAO Wei-yuan, CHAI Jia-hou, TANG Wei-ye, WANG Sa-sa, LI You, CHEN Ying. Effects of Pre-stretching Treatment on Conductive and Sensing Properties of Elastic Polypyrrole Filaments[J]. Polymer Bulletin, 2023,36(10):1330-1336. DOI: 10.14028/j.cnki.1003-3726.2023.10.009.
In order to explore the effect of pre-stretching treatment on the conductivity and sensing properties of polypyrrole elastic conductive filaments
polypyrrole-coated fibers with different weight gain ratios were obtained by pre-stretching the elastic filaments to different degrees during pyrrole polymerization. Its microscopic morphology was observed by scanning electron microscopy
and the electrical and sensing performances were tested and analyzed. The research results show that the resistance decreases with the increase of pre-stretch ratio (>70%). At 10% pre-stretch ratio
the polypyrrole layer is smoother
but has the best strain sensing performance: in the range of 0~2 cN
the internal sensitivity is high up to 7.68/N
and the sensitivity decreases and stabilizes at about 1/N after exceeding 2 cN. Both the repeatability experiment and the finger bending test show that the conductive filament pre-stretched by 10% has good sensitivity and sensing stability
and the resistance change rates are 24.71% and 11.01%
respectively. Therefore
the polypyrrole composite elastic filament with this structure is expected to be used in the detection of human motion and physiological signals. The elastic conductive yarns with higher pre-stretch ratios have a wrinkled structure on the surface
so they have the stable resistance value as stretched