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1..中国科学院化学研究所工程塑料重点实验室,北京 100190
2..中国石油天然气股份有限公司石油化工研究院,北京 102206
*李倩,E-mail: liqian2010@iccas.ac.cn
纸质出版日期:2024-04-20,
收稿日期:2023-09-19,
录用日期:2023-10-21
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吴世虎, 王科峰, 李倩, 李化毅. 微通道反应器中茂金属催化1-丁烯聚合研究. 高分子通报, 2024, 37(4), 486–490
Wu, S. H.; Wang, K. F.; Li, Q.; Li, H. Y. Study on solution polymerization of 1-butene catalyzed by metallocene in a microchannel reactor. Polym. Bull. (in Chinese), 2024, 37(4), 486–490
吴世虎, 王科峰, 李倩, 李化毅. 微通道反应器中茂金属催化1-丁烯聚合研究. 高分子通报, 2024, 37(4), 486–490 DOI: 10.14028/j.cnki.1003-3726.2024.23.318.
Wu, S. H.; Wang, K. F.; Li, Q.; Li, H. Y. Study on solution polymerization of 1-butene catalyzed by metallocene in a microchannel reactor. Polym. Bull. (in Chinese), 2024, 37(4), 486–490 DOI: 10.14028/j.cnki.1003-3726.2024.23.318.
以
rac
-Me
2
Si(2
5-Me
2
-4-Ph-ThCp)
2
ZrCl
2
茂金属为主催化剂,甲基铝氧烷(MAO)为助催化剂,二甲苯为溶液在1/8英寸不锈钢管搭建的微通道反应器中进行1-丁烯的溶液聚合。在本研究中,1-丁烯成功在微通道反应器的管道中实现连续聚合,并表征了所得聚合物的结构与性能。
Solution homopolymerization of 1-butene was performed in a microchannel reactor constructed of 1/8-inch stainless steel tube
using
rac
-Me
2
Si(2
5-Me
2
-4-Ph-ThCp)
2
ZrCl
2
metallocene as the main catalyst
methylaluminoxane (MAO) as the cocatalyst
and xylene as the solution. In this study
continuous polymerization of 1-butene was achieved in the microchannel reactor
and the structure and properties of the polybutylenes were characterized.
微通道反应器茂金属催化剂1-丁烯溶液聚合
Microchannel reactorMetallocene1-ButeneSolution polymerization
董小芳, 崔晓鹏, 王秀绘, 杨敏, 王斯晗, 刘宾元. 聚丁烯-1生产技术研究进展. 石油化工, 2017, 46(6), 810–816.
Tonhauser, C.; Natalello, A.; Löwe, H.; Frey, H. Microflow technology in polymer synthesis. Macromole-cules, 2012, 45(24), 9551–9570.
Baeten, E.; Verbraeken, B.; Hoogenboom, R.; Junkers, T. Continuous poly(2-oxazoline) triblock copolymer synthesis in a microfluidic reactor cascade. Chem. Commun., 2015, 51(58), 11701–11704.
朱丽萍, 李耀刚, 张青红, 王宏志, 朱美芳. 一种共轴微通道反应器设计及单分散生物质聚合物微珠的可控制备. 高分子学报, 2009, (11), 1132–1137.
Rubens, M.; Latsrisaeng, P.; Junkers, T. Visible light-induced iniferter polymerization of methacrylates enhan-ced by continuous flow. Polym. Chem., 2017, 8(42), 6496–6505.
缪世锋, 余金鹏, 关怡新, 姚善泾. T型微通道装置制备单分散PLGA微球. 高分子学报, 2012, (2), 154–159.
Rathi, N.; Gaikar, V. G. Optimization of continuous synthesis of cross-linked chitosan nanoparticles using microreactors. Chem. Eng. Technol., 2017, 40(3), 506–513.
袁炜, 刘卫卫, 李倩, 李化毅, 胡友良. 微反应器技术在聚合中的应用研究进展. 高分子通报, 2019, (1), 94–101.
Jähnisch, K.; Hessel, V.; Löwe, H.; Baerns, M. Chemistry in microstructured reactors. Angew. Chem. Int. Ed., 2004, 43(4), 406–446.
Nielsen, C. A.; Chrisman, R. W.; LaPointe, R. E.; Miller, T. E. Novel tubing microreactor for monitoring chemical reactions. Anal. Chem., 2002, 74(13), 3112–3117.
Beigzadeh, D.; Nielsen, C. Study of ethylene poly-merization under single liquid phase and vapor-liquid phase conditions in a continuous-flow tubular reactor. Chem. Eng. Technol., 2007, 30(8), 1088–1093.
Izmer, V. V.; Lebedev, A. Y.; Nikulin, M. V.; Ryabov, A. N.; Asachenko, A. F.; Lygin, A. V.; Sorokin, D. A.; Voskoboynikov, A. Z. Palladium-catalyzed pathways to aryl-substituted indenes: efficient synthesis of ligands and the respective ansa-zirconocenes. Organometallics, 2006, 25(5), 1217–1229.
吴世虎, 李倩, 李磊, 袁炜, 罗志, 李化毅, 鄢国平. 微通道反应器中茂金属催化的乙丙共聚合研究. 高分子通报, 2021, (6), 153–158.
Resconi, L.; Abis, L.; Franciscono, G. 1-Olefin polymerization at bis(pentamethylcyclopentadienyl)zirconium and -hafnium centers: enantioface selectivity. Macromolecules, 1992, 25(25), 6814–6817.
Resconi, L.; Camurati, I.; Malizia, F. Metallocene catalysts for 1-butene polymerization. Macromol. Chem. Phys., 2007, 208(4), 423.
Li, J. Q.; Guan, P. P.; Zhang, Y.; Xue, F. F.; Zhou, C. B.; Zhao, J.; Shang, Y. R.; Xue, M. L.; Yu, D. H.; Jiang, S. C. Shear effects on crystallization behaviors and structure transitions of isotactic poly-1-butene. J. Polym. Res., 2014, 21(9), 1–12.
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