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树状化核桃壳基催化剂的制备及其催化CO2与胺的甲酰化反应
Preparation of Imidazole Salt Dendrimers Functionalized Walnut Shell Powder-based Catalysts and Application in
N -formylation of CO2- 高分子通报 2024年37卷第10期 页码：1459-1469
- 作者机构：
1.华侨大学材料科学与工程学院，厦门 361021
2.中国科学院上海高等研究院，上海 201204
- 作者简介：
*熊兴泉，E-mail: xxqluli@hqu.edu.cn
- 基金信息：福建省“高校新世纪优秀人才支持计划”;“华侨大学中青年教师科研提升资助计划”(ZQN-YX103);福建省自然科学基金(2021J01294)
DOI：10.14028/j.cnki.1003-3726.2024.24.045
中图分类号：纸质出版日期：2024-10-20，
网络出版日期：2024-07-20，
收稿日期：2024-02-19，
录用日期：2024-05-23
- 稿件说明：
移动端阅览
赖石林, 陆颖琪, 张辉, 高利柱, 熊兴泉. 树状化核桃壳基催化剂的制备及其催化CO2与胺的甲酰化反应. 高分子通报, 2024, 37(10), 1459–1469
Lai, S. L.; Lu, Y. Q.; Zhang, H.; Gao, L. Z.; Xiong, X. Q. Preparation of imidazole salt dendrimers functionalized walnut shell powder-based catalysts and application in N-formylation of CO2. Polym. Bull. (in Chinese), 2024, 37(10), 1459–1469
赖石林, 陆颖琪, 张辉, 高利柱, 熊兴泉. 树状化核桃壳基催化剂的制备及其催化CO2与胺的甲酰化反应. 高分子通报, 2024, 37(10), 1459–1469 DOI： 10.14028/j.cnki.1003-3726.2024.24.045.
Lai, S. L.; Lu, Y. Q.; Zhang, H.; Gao, L. Z.; Xiong, X. Q. Preparation of imidazole salt dendrimers functionalized walnut shell powder-based catalysts and application in N-formylation of CO2. Polym. Bull. (in Chinese), 2024, 37(10), 1459–1469 DOI： 10.14028/j.cnki.1003-3726.2024.24.045.
摘要
以林产工业废弃物核桃壳粉(WS)为原料，通过对其进行多步化学改性，分别制备出外围被不同代数咪唑盐(IM)树状分子(WS-G
n
-FeCl
3
(
n
=1
2
3))功能化的催化剂载体(G
n
-IM (
n
=1
2
3))，然后将该系列载体分别负载FeCl
3
，制备出核桃壳粉基异相催化剂WS-G
n
-FeCl
3
(
n
=1
2
3)。通过采用傅里叶红外(FTIR)、热重分析(TG)、元素分析(EA)等对WS-G
n
-FeCl
3
(
n
=1
2
3)进行了表征分析。将所得催化剂应用于有机胺的甲酰化反应，结果表明树状分子代数对催化剂的催化活性有着重要影响，第三代催化剂WS-G3-FeCl
3
显示出最高催化活性。以WS-G3-FeCl
3
为催化剂催化有机胺与CO
2
之间的甲酰化反应，在100 ℃以及CO
2
氛围中(1.0 MPa)反应1 h，即可高效合成出甲酰胺类化合物，且WS-G3-FeCl
3
容易回收与重复使用，该催化剂在重复使用10次后活性没有明显的降低。
Abstract
Walnut shell (WS) powder
a kind of industrial waste of forest products
was used as raw material to prepare WS-based supports WS-G
n
-IM (
n
=1
2
3) functionalized with imidazole salt dendrimers by multi-step chemical modification
and then the WS-based heterogeneous catalysts WS-G
n
-FeCl
3
(
n
=1
2
3) were obtained by complexing WS-G
n
-IM (
n
=1
2
3) with FeCl
3
. WS-G
n
-FeCl
3
(
n
=1
2
3) were characterized by various characterization methods
such as Fourier-transform infrared (FTIR) spectroscopy
thermogravimetric analysis (TGA) and elemental analysis. In addition
WS-G
n
-FeCl
3
(
n
=1
2
3) were used in the catalytic
N
-formylation reaction with CO
2
. The results showed that the generation of imidazole salt dendrimers had an important influence on the catalytic activity of the catalysts
and WS-G3-FeCl
3
showed the highest
catalytic activity. Using WS-G3-FeCl
3
to catalyze the
N
-formylation reaction between organic amines and CO
2
(1.0 MPa)
formamide compounds can be efficiently synthesized at a temperature of 100 ℃ for 1 h. WS-G3-FeCl
3
could be easily recovered and reused at least 10 times without a significant reduction in activity.
关键词
核桃壳粉树状分子CO2甲酰胺异相催化
Keywords
Walnut shell powderDendrimersCO2N-formylationHeterogeneous catalysis
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