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1.中国科学院化学研究所,北京 100190
2.天津工业大学材料科学与工程学院,天津 300387
3.北京理工大学化学与化工学院,北京 100081
刘金宇(1991-),硕士研究生,主要从事高性能质子交换膜的制备、改性及应用;
*E-mail:wanglh@iccas.ac.cn.
纸质出版日期:2018-10-20,
收稿日期:2018-03-22,
修回日期:2018-04-18,
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刘金宇, 冯凯敏, 丁黎明, 王丽华, 韩旭彤, 黄庆林. 全钒液流电池用质子交换膜的研究进展[J]. 高分子通报, 2018,31(10):19-36.
Jin-yu LIU, Kai-min FENG, Li-ming DING, Li-hua WANG, Xu-tong HAN, Qin-lin HUANG. Research Advances of Proton Exchange Membranes for Vanadium Redox Flow Battery[J]. Polymer Bulletin, 2018,31(10):19-36.
刘金宇, 冯凯敏, 丁黎明, 王丽华, 韩旭彤, 黄庆林. 全钒液流电池用质子交换膜的研究进展[J]. 高分子通报, 2018,31(10):19-36. DOI: 10.14028/j.cnki.1003-3726.2018.10.003.
Jin-yu LIU, Kai-min FENG, Li-ming DING, Li-hua WANG, Xu-tong HAN, Qin-lin HUANG. Research Advances of Proton Exchange Membranes for Vanadium Redox Flow Battery[J]. Polymer Bulletin, 2018,31(10):19-36. DOI: 10.14028/j.cnki.1003-3726.2018.10.003.
全钒液流电池(VRFB)是一种大型储能装置,在新能源领域的发展和应用愈发成熟。在钒电池的组成中,质子交换膜(PEMs)作为关键部位之一,其性能优劣和成本决定着钒电池的寿命和最终性能。理想的钒电池隔膜不仅需要优异的质子传导能力,同时需要满足阻钒性、稳定性和成本合理性的要求。本文根据质子交换膜材料化学组成和物理结构的不同,对近几年钒电池用质子交换膜的研究现状及进展进行了分类总结和概述,同时阐述了高性能质子交换膜的重点研究及发展方向。
Vanadium redoxflow battery (VRFB) is a large-scale energy storage device
which has become increasingly mature in new energy field for the past few years. As the key composition of VRFB
the choice of proton exchange membranes(PEMs)has a great impact on the VRFB's performance and investment
an ideal PEM
not only perform the role of conducting protons
but also have the ability to prevent vanadium ions permeation
and should meet the requirements of physicochemical stability and acceptable cost at the same time. In this review
a detailed introduction about the latest progress in the field of PEMs for VRFB is given
based on the difference of chemical composition and physical structure of polymer materials. Finally
there is a highlight of the key research and development direction of PEMs in the future.
全钒液流电池质子交换膜研究现状
Vanadium redox flow batteryProton exchange membraneResearch status
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